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Structure and Hydrolysis of Heterovalent polynuclear Oxonitrocomplexes of Ptii,iv in Aqueous Solutions by 195Pt and 15N nmr Spectroscopy

Viktor Ivanovich Privalov 1
Viktor Ivanovich Privalov
, 
V V Lapkin 1
V V Lapkin
, 
Valery Pavlovich Tarasov 1
Valery Pavlovich Tarasov
, 
Yurii Aleksandrovich Buslaev 1
Yurii Aleksandrovich Buslaev
10.1070/MC1991v001n02ABEH000035
Published 1991-06-30
Communication , Volume 1, Issue 2, 59-61
6
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Privalov V. I. et al. Structure and Hydrolysis of Heterovalent polynuclear Oxonitrocomplexes of Ptii,iv in Aqueous Solutions by 195Pt and 15N nmr Spectroscopy // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 59-61.
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Privalov V. I., Lapkin V. V., Tarasov V. P., Buslaev Y. A. Structure and Hydrolysis of Heterovalent polynuclear Oxonitrocomplexes of Ptii,iv in Aqueous Solutions by 195Pt and 15N nmr Spectroscopy // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 59-61.
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TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000035
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000035
TI - Structure and Hydrolysis of Heterovalent polynuclear Oxonitrocomplexes of Ptii,iv in Aqueous Solutions by 195Pt and 15N nmr Spectroscopy
T2 - Mendeleev Communications
AU - Privalov, Viktor Ivanovich
AU - Lapkin, V V
AU - Tarasov, Valery Pavlovich
AU - Buslaev, Yurii Aleksandrovich
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 59-61
IS - 2
VL - 1
ER -
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@article{1991_Privalov,
author = {Viktor Ivanovich Privalov and V V Lapkin and Valery Pavlovich Tarasov and Yurii Aleksandrovich Buslaev},
title = {Structure and Hydrolysis of Heterovalent polynuclear Oxonitrocomplexes of Ptii,iv in Aqueous Solutions by 195Pt and 15N nmr Spectroscopy},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000035},
number = {2},
pages = {59--61},
doi = {10.1070/MC1991v001n02ABEH000035}
}
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Privalov, Viktor Ivanovich, et al. “Structure and Hydrolysis of Heterovalent polynuclear Oxonitrocomplexes of Ptii,iv in Aqueous Solutions by 195Pt and 15N nmr Spectroscopy.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 59-61. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000035.

Abstract

195Pt and 15N NMR chemical shifts and constants of scalar spin–spin coupling, 195Pt–15N and 195PtII–195PtIV, for the heterovalent platinum tetra- and hepta-meric oxonitrocomplexes [(NO2)6PtIV(μ-O)3PtII3(NO2)6]5− and [(NO2)6PtII3(μ-O)3PtIV(μ-O)3PtII3(NO2)6]8−, and for products of hydrolysis of these complexes have been obtained by 195Pt and 15N NMR spectroscopic studies on freshly prepared aqueous solutions and also on two month old solutions.

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