Home / Publications / Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings

Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings

Tengiz Shotaevich Kapanadze 1
Tengiz Shotaevich Kapanadze
,  , 
Yuri Vasil'evich Kokunov 1
Yuri Vasil'evich Kokunov
, 
Yurii Aleksandrovich Buslaev 1
Yurii Aleksandrovich Buslaev
10.1070/MC1991v001n02ABEH000032
Published 1991-06-30
Communication , Volume 1, Issue 2, 55-57
3
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kapanadze T. S. et al. Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 55-57.
GOST all authors (up to 50) Copy
Kapanadze T. S., Gorbunova Y. G., Kokunov Y. V., Buslaev Y. A. Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 55-57.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000032
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000032
TI - Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings
T2 - Mendeleev Communications
AU - Kapanadze, Tengiz Shotaevich
AU - Gorbunova, Yulia Germanovna
AU - Kokunov, Yuri Vasil'evich
AU - Buslaev, Yurii Aleksandrovich
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 55-57
IS - 2
VL - 1
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1991_Kapanadze,
author = {Tengiz Shotaevich Kapanadze and Yulia Germanovna Gorbunova and Yuri Vasil'evich Kokunov and Yurii Aleksandrovich Buslaev},
title = {Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000032},
number = {2},
pages = {55--57},
doi = {10.1070/MC1991v001n02ABEH000032}
}
MLA
Cite this
MLA Copy
Kapanadze, Tengiz Shotaevich, et al. “Stereochemistry of Cobalt(III) Complexes Containing (N,O)-Five and Six-membered Aminoalcohol Chelate Rings.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 55-57. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000032.

Abstract

59Cq NMR (94.45 MHz) has been used to study CoIII complexes formed by reaction of cobalt(II) chloride with 2- and 3-aminoalcohols; mononuclear molecular tris-O,N-chelate complexes of CoIIIL3 (L = NH2CH2CH2O– and NH2CH2CH2CH2O–) are produced in both geometric mer- and fac-forms, the mer-isomers being thermodynamically unstable and spontaneously rearranging to the fac-form in solution; the analogous complex L = NH2CHEtCH2O– exists only in the fac-form; 2-aminoalcohols also yield trinuclear complexes [CoII(CoIIIL3)2]2+, in which pseudo-contact interaction of the CoII and CoIII atoms occurs; the crystal structure of {CoII[CoIII(NH2CH2CH2O)3]2}·Cl3(NH3CH2CH2OH)·2H2O has been determined.

References

1.
10.1070/MC1991v001n02ABEH000032_bib1
Udavenko
Izv. Vyssh. Uchebn. Zaved, Khim. Khim. Tekhnol., 1963
2.
10.1070/MC1991v001n02ABEH000032_bib2
Udavenko
Zh. Neorg. Khim., 1969
3.
10.1070/MC1991v001n02ABEH000032_bib3
Evreev
Zh. Neorg. Khim., 1967
4.
10.1070/MC1991v001n02ABEH000032_bib4
Gulya
Dokl. Akad. Nauk SSSR, 1989
5.
10.1070/MC1991v001n02ABEH000032_bib5
Kapanadze
Dokl. Akad. Nauk SSSR, 1988
6.
10.1070/MC1991v001n02ABEH000032_bib6
Kapanadze
Koord. Khim., 1989
8.
10.1070/MC1991v001n02ABEH000032_bib8
Kapanadze
Zh. Neorg. Khim., 1990
9.
10.1070/MC1991v001n02ABEH000032_bib9
Udovenko
Zh. Neorg. Khim., 1967
10.
10.1070/MC1991v001n02ABEH000032_bib10
Gerasenkova
Zh. Neorg. Khim., 1970
12.
Trigonal prismatic cobalt(II) in a polynuclear complex
Bertrand J.A., Kelley J.A., Vassian E.G.
Journal of the American Chemical Society, 1969