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The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8

Igor Timofeevich Chizhevsky 1
Igor Timofeevich Chizhevsky
, 
Irina Anatol'evna Lobanova 1
Irina Anatol'evna Lobanova
, 
Vladimir Iosifovich Bregadze 1
Vladimir Iosifovich Bregadze
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
, 
Valentina A Antonovich 1
Valentina A Antonovich
, 
Aleksandr Vladimirovich Polyakov 1
Aleksandr Vladimirovich Polyakov
, 
Aleksandr Il'ich Yanovsky 1
Aleksandr Il'ich Yanovsky
, 
Yuri Timofeevich Struchkov 1
Yuri Timofeevich Struchkov
10.1070/MC1991v001n02ABEH000027
Published 1991-06-30
Communication , Volume 1, Issue 2, 47-49
46
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Chizhevsky I. T. et al. The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8 // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 47-49.
GOST all authors (up to 50) Copy
Chizhevsky I. T., Lobanova I. A., Bregadze V. I., Petrovskii P. V., Antonovich V. A., Polyakov A. V., Yanovsky A. I., Struchkov Y. T. The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8 // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 47-49.
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TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000027
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000027
TI - The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8
T2 - Mendeleev Communications
AU - Chizhevsky, Igor Timofeevich
AU - Lobanova, Irina Anatol'evna
AU - Bregadze, Vladimir Iosifovich
AU - Petrovskii, Pavel Vasil'evich
AU - Antonovich, Valentina A
AU - Polyakov, Aleksandr Vladimirovich
AU - Yanovsky, Aleksandr Il'ich
AU - Struchkov, Yuri Timofeevich
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 47-49
IS - 2
VL - 1
ER -
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@article{1991_Chizhevsky,
author = {Igor Timofeevich Chizhevsky and Irina Anatol'evna Lobanova and Vladimir Iosifovich Bregadze and Pavel Vasil'evich Petrovskii and Valentina A Antonovich and Aleksandr Vladimirovich Polyakov and Aleksandr Il'ich Yanovsky and Yuri Timofeevich Struchkov},
title = {The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000027},
number = {2},
pages = {47--49},
doi = {10.1070/MC1991v001n02ABEH000027}
}
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Chizhevsky, Igor Timofeevich, et al. “The First exo-nido-Ruthenacarborane Clusters. Synthesis and Molecular Structure of 5,6,10-[Cl(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-C2B9H8.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 47-49. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000027.

Abstract

Novel exo-nido-ruthenacarboranes, 5,6,10-[CI(Ph3P)2Ru]-5,6,10-μ-(H)3-10-H-7,8-R2C2B9H6 (1; R = H, structurally characterized by an X-ray diffraction study, and 2; R = Me) have been prepared by reaction of RuCl2 (PPh3)3 and [nido-7,8-R2C2B9H10]− K+ in diethyl ether-tetrahydrofuran; in the solid state clusters 1 and 2 contain tridentate nido–carborane ligands bound to the RuII atom through three Ru—H—B bridging hydrogen bonds, whereas in solution they exist as an equilibrium mixture of isomeric exo-nido-bis(triphenylphosphine)chlorohydridoruthenacarboranes formed as a result of the cleavage of one of the Ru—H—B bonds with the formation of a new Ru—B σ-bond and a simultaneous hydrogen atom shift to the metal atom.

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