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Different Behaviour of Fervenulin 4-Oxide and 1,3-Dimethyllumazine 5-Oxide towards Nucleophiles

Anna Vasil'evna Gulevskaya 1
Anna Vasil'evna Gulevskaya
, 
Alexander Fedorovich Pozharskii 1
Alexander Fedorovich Pozharskii
, 
Sergei Victorovich Shorshnev 2
Sergei Victorovich Shorshnev
, 
Valery Vasil'evich Kuz'menko 3
Valery Vasil'evich Kuz'menko
2 Ural Scientific Research Institute of Technology of Medical Preparations, Ekaterinburg, Russian Federation
10.1070/MC1991v001n02ABEH000026
Published 1991-06-30
Communication , Volume 1, Issue 2, 46-47
6
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Gulevskaya A. V. et al. Different Behaviour of Fervenulin 4-Oxide and 1,3-Dimethyllumazine 5-Oxide towards Nucleophiles // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 46-47.
GOST all authors (up to 50) Copy
Gulevskaya A. V., Pozharskii A. F., Shorshnev S. V., Kuz'menko V. V. Different Behaviour of Fervenulin 4-Oxide and 1,3-Dimethyllumazine 5-Oxide towards Nucleophiles // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 46-47.
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TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000026
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000026
TI - Different Behaviour of Fervenulin 4-Oxide and 1,3-Dimethyllumazine 5-Oxide towards Nucleophiles
T2 - Mendeleev Communications
AU - Gulevskaya, Anna Vasil'evna
AU - Pozharskii, Alexander Fedorovich
AU - Shorshnev, Sergei Victorovich
AU - Kuz'menko, Valery Vasil'evich
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 46-47
IS - 2
VL - 1
ER -
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@article{1991_Gulevskaya,
author = {Anna Vasil'evna Gulevskaya and Alexander Fedorovich Pozharskii and Sergei Victorovich Shorshnev and Valery Vasil'evich Kuz'menko},
title = {Different Behaviour of Fervenulin 4-Oxide and 1,3-Dimethyllumazine 5-Oxide towards Nucleophiles},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000026},
number = {2},
pages = {46--47},
doi = {10.1070/MC1991v001n02ABEH000026}
}
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Gulevskaya, Anna Vasil'evna, et al. “Different Behaviour of Fervenulin 4-Oxide and 1,3-Dimethyllumazine 5-Oxide towards Nucleophiles.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 46-47. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000026.

Abstract

Fervenulin 4-oxide reacts with secondary amines and carbanions to give derivatives of 1,3-dimethyl-5-nitroso-6-hydrazinouracil 9 and 10; under similar conditions 1,3-dimethyllumazine 5-oxide reacts with piperidine and morpholine to give products 14 in high yield, by nucleophilic substitution of hydrogen at C(6).

References

1.
10.1070/MC1991v001n02ABEH000026_bib1
Pozharskii
Khim. Geterotsikl. Soedin., 1988
4.
Synthese von Pteridin-N-oxyden [1]
Pfleiderer W., Hutzenlaub W.
Angewandte Chemie, 1965
5.
10.1070/MC1991v001n02ABEH000026_bib5
Gulevskaya
Khim. Geterotsikl. Soedin., 1990