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1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution

Dmitrii Georgievich Gusev 1
Dmitrii Georgievich Gusev
, 
Alexei Borisovich Vymenits 1
Alexei Borisovich Vymenits
, 
Vladimir Ivanovich Bakhmutov 1
Vladimir Ivanovich Bakhmutov
10.1070/MC1991v001n01ABEH000015
Published 1991-03-31
Communication , Volume 1, Issue 1, 24-26
2
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Gusev D. G., Vymenits A. B., Bakhmutov V. I. 1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 24-26.
GOST all authors (up to 50) Copy
Gusev D. G., Vymenits A. B., Bakhmutov V. I. 1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 24-26.
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TY - JOUR
DO - 10.1070/MC1991v001n01ABEH000015
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000015
TI - 1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution
T2 - Mendeleev Communications
AU - Gusev, Dmitrii Georgievich
AU - Vymenits, Alexei Borisovich
AU - Bakhmutov, Vladimir Ivanovich
PY - 1991
DA - 1991/03/31
PB - Mendeleev Communications
SP - 24-26
IS - 1
VL - 1
ER -
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@article{1991_Gusev,
author = {Dmitrii Georgievich Gusev and Alexei Borisovich Vymenits and Vladimir Ivanovich Bakhmutov},
title = {1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000015},
number = {1},
pages = {24--26},
doi = {10.1070/MC1991v001n01ABEH000015}
}
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Gusev, Dmitrii Georgievich, et al. “1H, 2H and 31P NMR Study of the Structure and Behaviour of lrH2Cl(HCl)(PPri3)2 in Solution.” Mendeleev Communications, vol. 1, no. 1, Mar. 1991, pp. 24-26. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000015.

Abstract

HCl coordination in lrH2Cl(HCl)(PPri3)2 and the reversible transformation of the complex into monohydride lrHCl2(PPri3)2 and dihydride lrH2Cl(PPri3)2 in solution have been confirmed by 1H, 2H and 31P NMR spectroscopy.

References

4.
Photochemical reactivity of 2[IrIIIHCl2(PPri3)2]·H2. Formation of monohydrido isomers of IrIIIand evidence of photoinduced oxidative addition of H2, to IrIII
Bergamini P., Sostero S., Traverso O., Mura P., Segre A.
Journal of the Chemical Society Dalton Transactions, 1989