Home / Publications / Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes

Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes

Oleg Vladimirovich Gusev 1
Oleg Vladimirovich Gusev
, 
Arkady Zinov'evich Rubezhov 1
Arkady Zinov'evich Rubezhov
, 
Jesus A Miguel-Garcia 2
Jesus A Miguel-Garcia
, 
Peter M Maitlis 2
Peter M Maitlis
10.1070/MC1991v001n01ABEH000013
Published 1991-03-31
Communication , Volume 1, Issue 1, 21-22
11
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Gusev O. V. et al. Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 21-22.
GOST all authors (up to 50) Copy
Gusev O. V., Rubezhov A. Z., Miguel-Garcia J. A., Maitlis P. M. Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 21-22.
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TY - JOUR
DO - 10.1070/MC1991v001n01ABEH000013
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000013
TI - Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes
T2 - Mendeleev Communications
AU - Gusev, Oleg Vladimirovich
AU - Rubezhov, Arkady Zinov'evich
AU - Miguel-Garcia, Jesus A
AU - Maitlis, Peter M
PY - 1991
DA - 1991/03/31
PB - Mendeleev Communications
SP - 21-22
IS - 1
VL - 1
ER -
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@article{1991_Gusev,
author = {Oleg Vladimirovich Gusev and Arkady Zinov'evich Rubezhov and Jesus A Miguel-Garcia and Peter M Maitlis},
title = {Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000013},
number = {1},
pages = {21--22},
doi = {10.1070/MC1991v001n01ABEH000013}
}
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Gusev, Oleg Vladimirovich, et al. “Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes.” Mendeleev Communications, vol. 1, no. 1, Mar. 1991, pp. 21-22. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000013.

Abstract

Reaction of [Rh(C5Me5)(C5H5)]+ with KOBut in tetrahydrofuran gives [Rh(C5Me4CH2)(C5H5)]; it reacts readily with halides (R—X) to give [Rh(C5Me4CH2R)(C5H5)]X, which can be converted into [Rh2(C5Me4CH2R)2Cl4].

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Journal of the Chemical Society Chemical Communications, 1990
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Tentacled iron sandwiches: peralkylation of FeIICp(C6Me6)+PF6–(Cp = C5H5)
Moulines F., Astruc D.
Journal of the Chemical Society Chemical Communications, 1989
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10.1070/MC1991v001n01ABEH000013_bib5_4
Vol’kenay
Izv. Akad. Nauk SSSR, Ser. Khim., 1987