Home / Publications / Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O

Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O

Inna Aleksandrovna Krol 1
Inna Aleksandrovna Krol
, 
Zoya Aleksandrovna Starikova 2
Zoya Aleksandrovna Starikova
, 
Vladimir Semenovich Sergienko 3
Vladimir Semenovich Sergienko
, 
Elena Okkasovna Tolkacheva 1
Elena Okkasovna Tolkacheva
10.1070/MC1991v001n01ABEH000005
Published 1991-03-31
Communication , Volume 1, Issue 1, 7-8
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Krol I. A. et al. Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 7-8.
GOST all authors (up to 50) Copy
Krol I. A., Starikova Z. A., Sergienko V. S., Tolkacheva E. O. Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 7-8.
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TY - JOUR
DO - 10.1070/MC1991v001n01ABEH000005
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000005
TI - Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O
T2 - Mendeleev Communications
AU - Krol, Inna Aleksandrovna
AU - Starikova, Zoya Aleksandrovna
AU - Sergienko, Vladimir Semenovich
AU - Tolkacheva, Elena Okkasovna
PY - 1991
DA - 1991/03/31
PB - Mendeleev Communications
SP - 7-8
IS - 1
VL - 1
ER -
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@article{1991_Krol,
author = {Inna Aleksandrovna Krol and Zoya Aleksandrovna Starikova and Vladimir Semenovich Sergienko and Elena Okkasovna Tolkacheva},
title = {Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000005},
number = {1},
pages = {7--8},
doi = {10.1070/MC1991v001n01ABEH000005}
}
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Krol, Inna Aleksandrovna, et al. “Deprotonation of an α-Hydroxy Group in 1-Hydroxyethylidenediphosphonic Acid and an Unusual Type of Dimeric Anion in the Structure of Na5[Mo2O6(L*)]·14H2O.” Mendeleev Communications, vol. 1, no. 1, Mar. 1991, pp. 7-8. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000005.

Abstract

The synthesis and X-ray analysis of a complex containing a deprotonated α-hydroxy group, Na5[Mo2O6(L*)]•14H2O, are presented; the dimeric anion has an unusual structure with a different number of terminal oxygen atoms in the ‘yl’ groups of the two moieties of the dimer (MoO3 and MoO2).

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