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The First Palladium Carbene Cluster: Synthesis and Structure

Tat'yana Alekseevna Stromnova 1
Tat'yana Alekseevna Stromnova
, 
Irina N Busygina 1
Irina N Busygina
, 
Dmitrii Ivanovich Kochubey 2
Dmitrii Ivanovich Kochubey
, 
Ilya Iosifovich Moiseev 1
Ilya Iosifovich Moiseev
10.1070/MC1991v001n01ABEH000001
Published 1991-03-31
Communication , Volume 1, Issue 1, 1-2
10
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Stromnova T. A. et al. The First Palladium Carbene Cluster: Synthesis and Structure // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 1-2.
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Stromnova T. A., Busygina I. N., Kochubey D. I., Moiseev I. I. The First Palladium Carbene Cluster: Synthesis and Structure // Mendeleev Communications. 1991. Vol. 1. No. 1. pp. 1-2.
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TY - JOUR
DO - 10.1070/MC1991v001n01ABEH000001
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000001
TI - The First Palladium Carbene Cluster: Synthesis and Structure
T2 - Mendeleev Communications
AU - Stromnova, Tat'yana Alekseevna
AU - Busygina, Irina N
AU - Kochubey, Dmitrii Ivanovich
AU - Moiseev, Ilya Iosifovich
PY - 1991
DA - 1991/03/31
PB - Mendeleev Communications
SP - 1-2
IS - 1
VL - 1
ER -
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@article{1991_Stromnova,
author = {Tat'yana Alekseevna Stromnova and Irina N Busygina and Dmitrii Ivanovich Kochubey and Ilya Iosifovich Moiseev},
title = {The First Palladium Carbene Cluster: Synthesis and Structure},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000001},
number = {1},
pages = {1--2},
doi = {10.1070/MC1991v001n01ABEH000001}
}
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Stromnova, Tat'yana Alekseevna, et al. “The First Palladium Carbene Cluster: Synthesis and Structure.” Mendeleev Communications, vol. 1, no. 1, Mar. 1991, pp. 1-2. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n01ABEH000001.

Abstract

The first palladium carbene cluster, μ2-tetrakis(diphenylmethylidene)-μ2-tetraacetato-quadro-tetrapalladiurn(4Pd–Pd) Pd4(μ-CPh2)4(μ-OAc)4, has been obtained by substitution of diphenylcarbene ligands for CO groups in μ2-tetrakis(carbonyl)-μ2-tetraacetato-quadro-tetrapalladium(4Pd–Pd) Pd4(μ-CO)4(μ-OAc)4; the cluster is also the first palladium complex containing carbene ligands of the Schrock type.

References

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Catalysis in C1 Chemistry, 1983
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Izv. Akad. Nauk SSSR, Ser. Khim., 1978
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New palladium carbonyl clusters: X-ray crystal structure of [Pd 4(CO)4(OAc)4]·(AcOH)2
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Journal of the Chemical Society Chemical Communications, 1978
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X-Ray Spectroscopy for Studying the Structure of Amorphous Solids. EXAFS Spectroscopy, 1988
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Synthesis and X-ray crystal and molecular structure of the palladium–molybdenum carbonyl cluster Na2{Pd4[CpMo(CO)3]4}·2THF (THF = tetrahydrofuran; Cp =η5-cyclopentadienyl)
Stromnova T.A., Busygina I.N., Katser S.B., Antsyshkina A.S., Porai-Koshits M.A., Moiseev I.I.
Journal of the Chemical Society Chemical Communications, 1988