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Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst

Sergey Aleksandrovich Rzhevskiy 1
Sergey Aleksandrovich Rzhevskiy
, 
Olga Vladimirovna Shurupova 1
Olga Vladimirovna Shurupova
, 
Andrey Fedorovich Asachenko 1, 2
Andrey Fedorovich Asachenko
, 
Nikita M Belov 2
Nikita M Belov
, 
Anna V Plutalova 2
Anna V Plutalova
,  ,  , 
Elena Vyacheslavna Chernikova 1, 2
Elena Vyacheslavna Chernikova
, 
Irina Petrovna Beletskaya 1, 2
Irina Petrovna Beletskaya
1 A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
2 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
3 M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
10.1016/j.mencom.2024.10.034
Published 2024-10-22
Communication , Volume 34, Issue 6, 878-880
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Rzhevskiy S. A. et al. Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 878-880.
GOST all authors (up to 50) Copy
Rzhevskiy S. A., Shurupova O. V., Asachenko A. F., Belov N. M., Plutalova A. V., Trofimchuk E. S., Toms R. V., Chernikova E. V., Beletskaya I. P. Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 878-880.
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TY - JOUR
DO - 10.1016/j.mencom.2024.10.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.034
TI - Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst
T2 - Mendeleev Communications
AU - Rzhevskiy, Sergey Aleksandrovich
AU - Shurupova, Olga Vladimirovna
AU - Asachenko, Andrey Fedorovich
AU - Belov, Nikita M
AU - Plutalova, Anna V
AU - Trofimchuk, Elena Sergeevna
AU - Toms, Roman Vladimirovich
AU - Chernikova, Elena Vyacheslavna
AU - Beletskaya, Irina Petrovna
PY - 2024
DA - 2024/10/22
PB - Mendeleev Communications
SP - 878-880
IS - 6
VL - 34
ER -
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@article{2024_Rzhevskiy,
author = {Sergey Aleksandrovich Rzhevskiy and Olga Vladimirovna Shurupova and Andrey Fedorovich Asachenko and Nikita M Belov and Anna V Plutalova and Elena Sergeevna Trofimchuk and Roman Vladimirovich Toms and Elena Vyacheslavna Chernikova and Irina Petrovna Beletskaya},
title = {Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.034},
number = {6},
pages = {878--880},
doi = {10.1016/j.mencom.2024.10.034}
}
MLA
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Rzhevskiy, Sergey Aleksandrovich, et al. “Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst.” Mendeleev Communications, vol. 34, no. 6, Oct. 2024, pp. 878-880. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.034.

Keywords

carbon dioxide
catalysis
cyclic carbonates
cyclodepolymerization
epoxides
polycarbonates
polymerization

Abstract

The racemic salen complex of cobalt(iii) with pentafluorobenzoate axial ligand provides the synthesis of high molecular weight amorphous polypropylene carbonate and its full conversion into propylene carbonate.

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