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Impact of electron transport layer uniformity on field-induced degradation of inverted perovskite solar cells

Nikita Alexandrovich Emelianov 1
Nikita Alexandrovich Emelianov
,  , 
Anastasia Andreevna Bizyaeva 1, 2
Anastasia Andreevna Bizyaeva
, 
Mikhail S Leshchev 1
Mikhail S Leshchev
, 
Pavel Anatol'evich Troshin 1, 3
Pavel Anatol'evich Troshin
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
3 Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou, China
10.1016/j.mencom.2024.10.024
Published 2024-10-22
Communication , Volume 34, Issue 6, 844-846
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Emelianov N. A. et al. Impact of electron transport layer uniformity on field-induced degradation of inverted perovskite solar cells // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 844-846.
GOST all authors (up to 50) Copy
Emelianov N. A., Ozerova V. V., Bizyaeva A. A., Leshchev M. S., Troshin P. A. Impact of electron transport layer uniformity on field-induced degradation of inverted perovskite solar cells // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 844-846.
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TY - JOUR
DO - 10.1016/j.mencom.2024.10.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.024
TI - Impact of electron transport layer uniformity on field-induced degradation of inverted perovskite solar cells
T2 - Mendeleev Communications
AU - Emelianov, Nikita Alexandrovich
AU - Ozerova, Victoria Victorovna
AU - Bizyaeva, Anastasia Andreevna
AU - Leshchev, Mikhail S
AU - Troshin, Pavel Anatol'evich
PY - 2024
DA - 2024/10/22
PB - Mendeleev Communications
SP - 844-846
IS - 6
VL - 34
ER -
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@article{2024_Emelianov,
author = {Nikita Alexandrovich Emelianov and Victoria Victorovna Ozerova and Anastasia Andreevna Bizyaeva and Mikhail S Leshchev and Pavel Anatol'evich Troshin},
title = {Impact of electron transport layer uniformity on field-induced degradation of inverted perovskite solar cells},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.024},
number = {6},
pages = {844--846},
doi = {10.1016/j.mencom.2024.10.024}
}
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Emelianov, Nikita Alexandrovich, et al. “Impact of electron transport layer uniformity on field-induced degradation of inverted perovskite solar cells.” Mendeleev Communications, vol. 34, no. 6, Oct. 2024, pp. 844-846. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.024.

Keywords

electric field-induced degradation
electron transport materials
PC61BM
perovskite solar cells
pyrrolidinofullerenes

Abstract

The impact of different electron transport layers (ETLs) based on fullerene derivatives, such as the well-known PC61BM and promising 3-pyridyl-substituted pyrrolidino[60]fullerene (PYF-30), on the electric field-induced degradation of inverted perovskite solar cells has been demonstrated. Devices assembled using PYF-30 and PC61BM deposited from deuterated chloroform exhibit significantly higher stability compared to PC61BM films deposited from chlorobenzene. The main reason for the decrease in the efficiency of the device during aging is the formation of pinhole-type defects in the ETL caused by the agglomeration of molecules of fullerene derivatives.

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