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Mn-catalyzed syngas-assisted reductive Knoevenagel condensation

Ivan Vladimirovich Smirnov 1, 2
Ivan Vladimirovich Smirnov
Oleg Ilyich Afanasyev
Klim Olegovich Biriukov 1
Klim Olegovich Biriukov
Maria Igorevna Godovikova 1
Maria Igorevna Godovikova
Denis Alexandrovich Chusov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
3 G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
Published 2024-10-22
CommunicationVolume 34, Issue 6, 831-833
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Smirnov I. V. et al. Mn-catalyzed syngas-assisted reductive Knoevenagel condensation // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 831-833.
GOST all authors (up to 50) Copy
Smirnov I. V., Afanasyev O. I., Biriukov K. O., Godovikova M. I., Chusov D. A. Mn-catalyzed syngas-assisted reductive Knoevenagel condensation // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 831-833.
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TY - JOUR
DO - 10.1016/j.mencom.2024.10.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.020
TI - Mn-catalyzed syngas-assisted reductive Knoevenagel condensation
T2 - Mendeleev Communications
AU - Smirnov, Ivan Vladimirovich
AU - Afanasyev, Oleg Ilyich
AU - Biriukov, Klim Olegovich
AU - Godovikova, Maria Igorevna
AU - Chusov, Denis Alexandrovich
PY - 2024
DA - 2024/10/22
PB - Mendeleev Communications
SP - 831-833
IS - 6
VL - 34
ER -
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@article{2024_Smirnov,
author = {Ivan Vladimirovich Smirnov and Oleg Ilyich Afanasyev and Klim Olegovich Biriukov and Maria Igorevna Godovikova and Denis Alexandrovich Chusov},
title = {Mn-catalyzed syngas-assisted reductive Knoevenagel condensation},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.020},
number = {6},
pages = {831--833},
doi = {10.1016/j.mencom.2024.10.020}
}
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Smirnov, Ivan Vladimirovich, et al. “Mn-catalyzed syngas-assisted reductive Knoevenagel condensation.” Mendeleev Communications, vol. 34, no. 6, Oct. 2024, pp. 831-833. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.020.

Keywords

C–C bond formation
cyanoacetates
Knoevenagel condensation
manganese catalysis
reduction
syngas

Abstract

Arene manganese π-complex was applied as a catalyst for the reductive Knoevenagel condensation. Syngas was used as a selective synergistic reducing agent providing the possibility to use 3d metal-based catalyst in such process. Demonstrated substrate scope indicates a high potential for this reaction in a medicinal chemistry.

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