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A novel mechanochemical synthesis of cyclopentadienyl-type Ni/NHC complexes

Oleg Vladimirovich Khazipov 1
Oleg Vladimirovich Khazipov
, 
Anastasia Sergeevna Pyatachenko 1
Anastasia Sergeevna Pyatachenko
, 
Viktor Mikhailovich Chernyshev 1
Viktor Mikhailovich Chernyshev
1 Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
10.1016/j.mencom.2024.10.017
Published 2024-10-22
Communication , Volume 34, Issue 6, 822-824
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Khazipov O. V., Pyatachenko A. S., Chernyshev V. M. A novel mechanochemical synthesis of cyclopentadienyl-type Ni/NHC complexes // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 822-824.
GOST all authors (up to 50) Copy
Khazipov O. V., Pyatachenko A. S., Chernyshev V. M. A novel mechanochemical synthesis of cyclopentadienyl-type Ni/NHC complexes // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 822-824.
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TY - JOUR
DO - 10.1016/j.mencom.2024.10.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.017
TI - A novel mechanochemical synthesis of cyclopentadienyl-type Ni/NHC complexes
T2 - Mendeleev Communications
AU - Khazipov, Oleg Vladimirovich
AU - Pyatachenko, Anastasia Sergeevna
AU - Chernyshev, Viktor Mikhailovich
PY - 2024
DA - 2024/10/22
PB - Mendeleev Communications
SP - 822-824
IS - 6
VL - 34
ER -
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@article{2024_Khazipov,
author = {Oleg Vladimirovich Khazipov and Anastasia Sergeevna Pyatachenko and Viktor Mikhailovich Chernyshev},
title = {A novel mechanochemical synthesis of cyclopentadienyl-type Ni/NHC complexes},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.017},
number = {6},
pages = {822--824},
doi = {10.1016/j.mencom.2024.10.017}
}
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Khazipov, Oleg Vladimirovich, et al. “A novel mechanochemical synthesis of cyclopentadienyl-type Ni/NHC complexes.” Mendeleev Communications, vol. 34, no. 6, Oct. 2024, pp. 822-824. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.017.

Keywords

azolium salts
ball milling.
ligands
mechanochemical synthesis
N-heterocyclic carbene
nickel complexes

Abstract

A user-friendly and highly efficient mechanochemical synthesis of Ni/NHC complexes of the general formula (NHC)Ni(Cp)Cl (NHC is an N-heterocyclic carbene ligand; Cp is the cyclopentadienyl anion) under aerobic conditions is reported. The reaction between nickelocene and azolium salts (NHC proligands) proceeds with good to excellent yields of (NHC)Ni(Cp)Cl in the presence of a K2CO3 additive, which reduces the clumping of the reaction mixture. The developed process can be scaled up on a planetary ball mill.

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