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Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties

Kirill Vladimirovich Zaitsev 1
Kirill Vladimirovich Zaitsev
, 
Andrei Dmitrievich Trubachev 1
Andrei Dmitrievich Trubachev
, 
Victor Aleksandrovich Tafeenko 1
Victor Aleksandrovich Tafeenko
, 
Yurii Fedorovich Oprunenko 1
Yurii Fedorovich Oprunenko
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.10.016
Published 2024-10-22
Communication , Volume 34, Issue 6, 819-821
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Zaitsev K. V. et al. Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 819-821.
GOST all authors (up to 50) Copy
Zaitsev K. V., Trubachev A. D., Tafeenko V. A., Oprunenko Y. F. Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties // Mendeleev Communications. 2024. Vol. 34. No. 6. pp. 819-821.
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TY - JOUR
DO - 10.1016/j.mencom.2024.10.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.016
TI - Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties
T2 - Mendeleev Communications
AU - Zaitsev, Kirill Vladimirovich
AU - Trubachev, Andrei Dmitrievich
AU - Tafeenko, Victor Aleksandrovich
AU - Oprunenko, Yurii Fedorovich
PY - 2024
DA - 2024/10/22
PB - Mendeleev Communications
SP - 819-821
IS - 6
VL - 34
ER -
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@article{2024_Zaitsev,
author = {Kirill Vladimirovich Zaitsev and Andrei Dmitrievich Trubachev and Victor Aleksandrovich Tafeenko and Yurii Fedorovich Oprunenko},
title = {Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.016},
number = {6},
pages = {819--821},
doi = {10.1016/j.mencom.2024.10.016}
}
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Zaitsev, Kirill Vladimirovich, et al. “Bis(triazole) derivatives of organodigermanes: synthesis, structure, and properties.” Mendeleev Communications, vol. 34, no. 6, Oct. 2024, pp. 819-821. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.10.016.

Keywords

click chemistry
group 14 elements
optical properties.
organogermanium compounds
XRD analysis

Abstract

The synthesis and molecular structure of the triazole- containing organodigermane [(4,1-BnC2HN3)Ph2Ge]2 (C2HN3 is 1,2,3-triazole-4,1-diyl) obtained under various conditions of the copper(i)-azide/alkyne cycloaddition are reported. Effective σ,π-conjugation in the compound between Ge-Ge, aryl and heterocyclic groups was established. The optical properties (absorption and fluorescence) of the digermane in MeCN and MeCN/H2O were evaluated, indicating the influence of the solvent.

References

.
Germanium Complexes with ONO Tridentate Ligands: O-H Bond Activation Control According to DFT Calculations
Zaitsev K.V., Trubachev A.D., Poleshchuk O.K.
International Journal of Molecular Sciences, 2023
.
Oligothienyl catenated germanes and silanes: Synthesis, structure, and properties
Zaitsev K.V., Lam K., Poleshchuk O.K., Kuz'mina L.G., Churakov A.V.
Dalton Transactions, 2018
.
Molecular Oligogermanes and Related Compounds: Structure, Optical and Semiconductor Properties
Zaitsev K.V., Tafeenko V.A., Oprunenko Y.F., Kharcheva A.V., Zhanabil Z., Suleimen Y., Lam K., Zaitsev V.B., Zaitseva A.V., Zaitseva G.S., Karlov S.S.
Chemistry - An Asian Journal, 2017
.
Silane and Germane Molecular Electronics
Su T.A., Li H., Klausen R.S., Kim N.T., Neupane M., Leighton J.L., Steigerwald M.L., Venkataraman L., Nuckolls C.
Accounts of Chemical Research, 2017
.
Single-Molecule Conductance in Atomically Precise Germanium Wires
Su T.A., Li H., Zhang V., Neupane M., Batra A., Klausen R.S., Kumar B., Steigerwald M.L., Venkataraman L., Nuckolls C.
Journal of the American Chemical Society, 2015
.
Copper-catalysed azide–alkyne cycloadditions (CuAAC): an update
Haldón E., Nicasio M.C., Pérez P.J.
Organic and Biomolecular Chemistry, 2015
.
Organogermanium suppresses cell death due to oxidative stress in normal human dermal fibroblasts
Takeda T., Doiyama S., Azumi J., Shimada Y., Tokuji Y., Yamaguchi H., Nagata K., Sakamoto N., Aso H., Nakamura T.
Scientific Reports, 2019
.
Fedulin A.I., Oprunenko Y.F., Karlov S.S., Zaitseva G.S., Zaitsev K.V.
Mendeleev Communications, 2021
.
Copper(i) acetate-catalyzed azide–alkyne cycloaddition for highly efficient preparation of 1-(pyridin-2-yl)-1,2,3-triazoles
Zhang Q., Wang X., Cheng C., Zhu R., Liu N., Hu Y.
Organic and Biomolecular Chemistry, 2012
.
Structural Motifs in Aryl Organogermanium Ge-O Derivatives for Material Design
Zaitsev K.V., Makarov I.S., Oprunenko Y.F., Tafeenko V.A., Lermontova E.K., Churakov A.V.
International Journal of Molecular Sciences, 2023
.
Ignatyev I.S., Kondratenko Y.A., Lezov D.V., Ugolkov V.L., Kochina T.A.
Mendeleev Communications, 2023
.
1,2‐Bis(triazolyl)tetraphenyldigermanes: Synthesis, Structure and Properties
Zaitsev K.V., Veshchitsky G.A., Oprunenko Y.F., Kharcheva A.V., Moiseeva A.A., Gloriozov I.P., Lermontova E.K.
Chemistry - An Asian Journal, 2023
.
Recent Developments with Organogermanes: their Preparation and Application in Synthesis and Catalysis
Rogova T., Ahrweiler E., Schoetz M.D., Schoenebeck F.
Angewandte Chemie - International Edition, 2023
.
Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction
Basu D., Ghosh B., Srivastava D., Patra N., Nayek H.P.
Dalton Transactions, 2024
.
Triply Selective & Sequential Diversification at Csp3: Expansion of Alkyl Germane Reactivity for C‐C & C‐Heteroatom Bond Formation
Ahrweiler E., Schoetz M.D., Singh G., Bindschaedler Q.P., Sorroche A., Schoenebeck F.
Angewandte Chemie - International Edition, 2024
.
Polydentate Amidinato‐Silylenes, ‐Germylenes and ‐Stannylenes
Cabeza J.A., García-Álvarez P.
Chemistry - A European Journal, 2024