Keywords
carboxylate complexes
platinum
pyridine
synthesis
XRD analysis.
Abstract
Two novel synthetic routes were suggested for square-planar carboxylic platinum(ii) complexes with acetic, pivalic, and benzoic ligands. In the first method, heating ionic complex [Py4Pt](OAc)2 under reduced pressure gives a molecular compound trans-[Py2Pt(OAc)2] with a moderate yield. In the second method, the same starting compound [Py4Pt](OAc)2 ∙ 6 H2O is melted with pivalic or benzoic acids, which leads to analogous carboxylic trans-complexes with almost quantitative yields.
References
.
Sheldrick G.M.
Acta crystallographica. Section C, Structural chemistry,
2015
.
Sheldrick G.M.
Acta Crystallographica Section A: Foundations and Advances,
2015
.
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography,
2009
.
![Two-way synthesis of a double-lantern heterobimetallic complex [Pd(μ-OOCMe)4Co]2(μ-OOCMe)2Pd(py)2](/storage/images/resized/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_small_thumb.webp)
Nefedov S.E., Yakushev I.A., Kozitsyna N.Y., Dobrokhotova Z.V., Ikorsky V.N., Vargaftik M.N., Moiseev I.I.
Inorganic Chemistry Communication,
2007
.
Cherkashina N.V., Kochubey D.I., Kanazhevskiy V.V., Zaikovskii V.I., Ivanov V.K., Markov A.A., Klyagina A.P., Dobrokhotova Z.V., Kozitsyna N.Y., Baranovsky I.B., Ellert O.G., Efimov N.N., Nefedov S.E., Novotortsev V.M., Vargaftik M.N., et. al.
Inorganic Chemistry,
2014
.
Yakushev I.A., Dyuzheva M.A., Stebletsova I.A., Kornev A.B., Cherkashina N.V., Vargaftik M.N.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya,
2022
.
Popova A.S., Ogarkova N.K., Shapovalov S.S., Skabitsky I.V., Kultyshkina E.K., A.Yakushev I., Vargaftik M.N.
Mendeleev Communications,
2022
.
Yakushev I.A., Nesterenko M.Y., Dorovatovskii P.V., Kornev A.B., Maksimova A.D., Popova A.S., Cherkashina N.V., Churakov A.V., Vargaftik M.N.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya,
2022
.
Yakushev I.A., Stolarov I.P., Cherkashina N.V., Churakov A.V., Zubavichus Y.V., Markov A.A., Gekhman A.E., Vargaftik M.N.
Inorganica Chimica Acta,
2020
.
Cherkashina N.V., Churakov A.V., Yakushev I.A., Stolyarov I.P., Khrustalev V.N., Khramov E.V., Markov A.A., Smirnova N.S., Zubavichus Y.V., Dorovatovskii P.V., Dobrokhotova Z.V., Ilyukhin A.B., Vargaftik M.N.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya,
2019
.
Stolyarov I.P., Cherkashina N.V., Churakov A.V., Naumkin A.V., Kornev A.B., Chernyak A.V., Martynenko V.M.
Russian Journal of Inorganic Chemistry,
2019
.
Pasynskii A.A., Shapovalov S.S., Skabitskii I.V., Tikhonova O.G.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya,
2016
.
Markov A.A., Yakushev I.A., Churakov A.V., Khrustalev V.N., Cherkashina N.V., Stolarov I.P., Gekhman A.E., Vargaftik M.N.
Mendeleev Communications,
2019
.
Carrondo M.A., Skapski A.C.
Acta Crystallographica Section B,
1978
.
Stephenson T.A., Morehouse S.M., Powell A.R., Heffer J.P., Wilkinson G.
Journal of the Chemical Society (Resumed),
1965
.
Zadesenets A., Filatov E., Plyusnin P., Baidina I., Dalezky V., Shubin Y., Korenev S., Bogomyakov A.
Polyhedron,
2011
.
Kabsch W.
Acta Crystallographica Section D Biological Crystallography,
2010
.
Svetogorov R.D., Dorovatovskii P.V., Lazarenko V.A.
Crystal Research and Technology,
2020
.
Kravtsova S.V., Romm I.P., Stash A.I., Belsky V.K.
Acta Crystallographica Section C Crystal Structure Communications,
1996
.
Vasilchenko D., Berdyugin S., Komarov V., Sheven D., Kolesov B., Filatov E., Tkachev S.
Inorganic Chemistry,
2022
.
Seah J.W., Lee J.X., Li Y., Pullarkat S.A., Tan N.S., Leung P.
Inorganic Chemistry,
2021
.
Steinhoff B.A., Guzei I.A., Stahl S.S.
Journal of the American Chemical Society,
2004
.
Woolley M.J., Khairallah G.N., da Silva G., Donnelly P.S., Yates B.F., O’Hair R.A.
Organometallics,
2013
.
Asanova T.I., Fedorova E.A., Asanov I.P., Yusenko K.V., Gerasimov E.Y., La Fontaine C., Roudenko O., Vasilchenko D.B., Korenev S.V.
Vacuum,
2021
.
Yakushev I.A., Ogarkova N.K., Khramov E.V., Smirnova N.S., Yu. Nesterenko M., Cherkashina N.V., Medvedev A.G., Panina M.V., Vargaftik M.N., Popova A.S.
Mendeleev Communications,
2023