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Alkylphenyl-substituted imidazolines as corrosion inhibitors: experimental and DFT study

Daniil Romanovich Bazanov 1
Daniil Romanovich Bazanov
,  , 
Natalia Alexandrovna Lozinskaya 1
Natalia Alexandrovna Lozinskaya
, 
Tatyana Eduardovna Andreeva 2
Tatyana Eduardovna Andreeva
, 
Yurii Igorevich Kuznetsov 2
Yurii Igorevich Kuznetsov
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
2 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2024.09.041
Published 2024-09-09
Communication , Volume 34, Issue 5, 751-754
2
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Bazanov D. R. et al. Alkylphenyl-substituted imidazolines as corrosion inhibitors: experimental and DFT study // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 751-754.
GOST all authors (up to 50) Copy
Bazanov D. R., Avdeev Y. G., Lozinskaya N. A., Andreeva T. E., Kuznetsov Y. I. Alkylphenyl-substituted imidazolines as corrosion inhibitors: experimental and DFT study // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 751-754.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.041
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.041
TI - Alkylphenyl-substituted imidazolines as corrosion inhibitors: experimental and DFT study
T2 - Mendeleev Communications
AU - Bazanov, Daniil Romanovich
AU - Avdeev, Yaroslav Gennadievich
AU - Lozinskaya, Natalia Alexandrovna
AU - Andreeva, Tatyana Eduardovna
AU - Kuznetsov, Yurii Igorevich
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 751-754
IS - 5
VL - 34
ER -
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@article{2024_Bazanov,
author = {Daniil Romanovich Bazanov and Yaroslav Gennadievich Avdeev and Natalia Alexandrovna Lozinskaya and Tatyana Eduardovna Andreeva and Yurii Igorevich Kuznetsov},
title = {Alkylphenyl-substituted imidazolines as corrosion inhibitors: experimental and DFT study},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.041},
number = {5},
pages = {751--754},
doi = {10.1016/j.mencom.2024.09.041}
}
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Bazanov, Daniil Romanovich, et al. “Alkylphenyl-substituted imidazolines as corrosion inhibitors: experimental and DFT study.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 751-754. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.041.
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Keywords

2-imidazolines
corrosion inhibitors
DFT designing corrosion inhibitors
hydrochloric corrosion
metal protection
metal surface adsorption.

Abstract

A series of steel corrosion inhibitors based on poly(alkyl-phenyl)-2-imidazolines was synthesized from available reagents. Electronic parameters that influence binding to a metal surface have been determined, and the influence of substituents on the geometry of binding to the surface has been studied. The resulting compounds have a degree of protection of steel in hydrochloric acid solutions in individual form above 98% at 60 °C and in a mixture with urotropine more than 99% at 95 °C.

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