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Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex

Inessa Aleksandrovna Efimenko 1
Inessa Aleksandrovna Efimenko
, 
Alexey Sergeevich Kubasov 1
Alexey Sergeevich Kubasov
, 
Nina Aleksandrovna Ivanova 1
Nina Aleksandrovna Ivanova
, 
Olga Sergeevna Erofeeva 1
Olga Sergeevna Erofeeva
, 
Ludmila Ivanovna Demina 2
Ludmila Ivanovna Demina
2 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2024.09.040
Published 2024-09-09
Communication , Volume 34, Issue 5, 748-750
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Efimenko I. A. et al. Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 748-750.
GOST all authors (up to 50) Copy
Efimenko I. A., Kubasov A. S., Ivanova N. A., Erofeeva O. S., Demina L. I. Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 748-750.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.040
TI - Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex
T2 - Mendeleev Communications
AU - Efimenko, Inessa Aleksandrovna
AU - Kubasov, Alexey Sergeevich
AU - Ivanova, Nina Aleksandrovna
AU - Erofeeva, Olga Sergeevna
AU - Demina, Ludmila Ivanovna
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 748-750
IS - 5
VL - 34
ER -
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@article{2024_Efimenko,
author = {Inessa Aleksandrovna Efimenko and Alexey Sergeevich Kubasov and Nina Aleksandrovna Ivanova and Olga Sergeevna Erofeeva and Ludmila Ivanovna Demina},
title = {Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.040},
number = {5},
pages = {748--750},
doi = {10.1016/j.mencom.2024.09.040}
}
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Efimenko, Inessa Aleksandrovna, et al. “Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 748-750. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.040.

Keywords

acetone condensation
one-step reaction
η3-allyl ligand
η3-allyl Pdii complex

Abstract

A one-step reaction was discovered giving the h3-allyl complex [Pd(h3-C6H9O)(μ-Cl)]2. The formation of the substituted h3-allyl ligand in the complex occurs as a result of the condensation of acetone at room temperature in a solution containing [Pd(PhCN)2Cl2] and organic acids. The structure of the resulting Pdii complex was determined by single crystal X-ray diffraction analysis.

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