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X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN

Boris Aleksandrovich Gostevsky 1
Boris Aleksandrovich Gostevsky
, 
Alexander Valentinovich Vashchenko 1
Alexander Valentinovich Vashchenko
, 
Nataliya Fedorovna Lazareva 1
Nataliya Fedorovna Lazareva
10.1016/j.mencom.2024.09.039
Published 2024-09-09
Communication , Volume 34, Issue 5, 745-747
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Gostevsky B. A., Vashchenko A. V., Lazareva N. F. X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 745-747.
GOST all authors (up to 50) Copy
Gostevsky B. A., Vashchenko A. V., Lazareva N. F. X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 745-747.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.039
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.039
TI - X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN
T2 - Mendeleev Communications
AU - Gostevsky, Boris Aleksandrovich
AU - Vashchenko, Alexander Valentinovich
AU - Lazareva, Nataliya Fedorovna
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 745-747
IS - 5
VL - 34
ER -
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@article{2024_Gostevsky,
author = {Boris Aleksandrovich Gostevsky and Alexander Valentinovich Vashchenko and Nataliya Fedorovna Lazareva},
title = {X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.039},
number = {5},
pages = {745--747},
doi = {10.1016/j.mencom.2024.09.039}
}
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Gostevsky, Boris Aleksandrovich, et al. “X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 745-747. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.039.

Keywords

acetonitrile.
crystal solvate
five-membered rings
pentacoordination
Si–Hal bond
Si⋯N interaction
silatranes
X-ray diffraction analysis

Abstract

The single-crystal X-ray study of ClSi(OCH2CH2)3N showed the formation of a cluster of three silatrane molecules with one acetonitrile molecule featuring hypercoordinated Si atoms in a trigonal-bipyramidal coordination environment with O atom in the equatorial plane. A number of solid-phase structural parameters and the conformation of the fivemembered rings of 1-chlorosilatrane were thus clarified.

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