Home / Publications / Formation of active centers of polymer catalysts for radical-coordination polymerization

Formation of active centers of polymer catalysts for radical-coordination polymerization

Olga Yurievna Vdovina 1
Olga Yurievna Vdovina
, 
Ruslan Rinatovich Galimullin 1
Ruslan Rinatovich Galimullin
, 
Marat F Abdullin 1
Marat F Abdullin
, 
Alexander Vadimovich Smirnov 1
Alexander Vadimovich Smirnov
, 
Sergei Viktorovich Kolesov 1
Sergei Viktorovich Kolesov
1 Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
10.1016/j.mencom.2024.09.031
Published 2024-09-09
Communication , Volume 34, Issue 5, 721-724
0
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Vdovina O. Y. et al. Formation of active centers of polymer catalysts for radical-coordination polymerization // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 721-724.
GOST all authors (up to 50) Copy
Vdovina O. Y., Galimullin R. R., Abdullin M. F., Smirnov A. V., Kolesov S. V. Formation of active centers of polymer catalysts for radical-coordination polymerization // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 721-724.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2024.09.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.031
TI - Formation of active centers of polymer catalysts for radical-coordination polymerization
T2 - Mendeleev Communications
AU - Vdovina, Olga Yurievna
AU - Galimullin, Ruslan Rinatovich
AU - Abdullin, Marat F
AU - Smirnov, Alexander Vadimovich
AU - Kolesov, Sergei Viktorovich
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 721-724
IS - 5
VL - 34
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Vdovina,
author = {Olga Yurievna Vdovina and Ruslan Rinatovich Galimullin and Marat F Abdullin and Alexander Vadimovich Smirnov and Sergei Viktorovich Kolesov},
title = {Formation of active centers of polymer catalysts for radical-coordination polymerization},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.031},
number = {5},
pages = {721--724},
doi = {10.1016/j.mencom.2024.09.031}
}
MLA
Cite this
MLA Copy
Vdovina, Olga Yurievna, et al. “Formation of active centers of polymer catalysts for radical-coordination polymerization.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 721-724. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.031.

Keywords

electrospray ionization
ferrocene
quantum-chemical modeling.
radical polymerization
reaction mechanisms

Abstract

Chromatography-mass spectrometry of samples representing the interaction products of ferrocene, radical initiator and monomer taken in the molar ratio of 1:2:10 in toluene solution was used for experimental detection of products indicating the structure and mechanism of formation of metal complex active centers of radical-coordination polymerization. Structures similar to those proposed by the quantum-chemical modeling were demonstrated to be formed with the participation of secondary radicals.

References

.
Generalized Gradient Approximation Made Simple
Perdew J.P., Burke K., Ernzerhof M.
Physical Review Letters, 1996
.
Effect of ferrocene on the synthesis of graft copolymers of vinylpolysiloxane and styrene
Masloborodova E.A., Kaganova E.V., Gusakova N.S., Agibalova L.V., Maretina E.Y., Baranets I.V., Islamova R.M.
Russian Journal of General Chemistry, 2017
.
Iron Catalysts in Atom Transfer Radical Polymerization
Dadashi-Silab S., Matyjaszewski K.
Molecules, 2020
.
Cobalt and manganese complexes with redox-active ligands in polymerization of acrylonitrile and methyl methacrylate
Kolyakina E.V., Gruzdeva L.N., Poddel´sky A.I., Grishin D.F.
Russian Chemical Bulletin, 2017
.
Manganese complexes with different ligand environments in the polymerization of methyl methacrylate and styrene
Kolyakina E.V., Gruzdeva L.N., Kreyndlin A.Z., Shtel´tser N.A., Grishin D.F.
Russian Chemical Bulletin, 2017
.
Ferrocenyl-containing iron(ii) clathrochelate-benzoyl peroxide, a new initiating system for radical polymerization of methyl methacrylate
Monakov Y.B., Islamova R.M., Sadykova G.R., Makarov I.S., Voloshin Y.Z., Bubnov Y.N.
Russian Chemical Bulletin, 2009
.
A study of the radical polymerization of styrene in the presence of ferrocene
Friesen A.K., Khursan S.L., Kolesov S.V., Monakov Y.B.
Russian Journal of Physical Chemistry B, 2011
.
Radical polymerization of methyl methacrylate in the presence of methylene blue and organobromides under visible light irradiation
Grishin D.F., Lizyakina O.S., Vaganova L.B., Kaltenberg A.A., Grishin I.D.
Iranian Polymer Journal (English Edition), 2021
.
Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene
Tereshchenko K.A., Shiyan D.A., Ulitin N.V., Kolesov S.V., Khursan S.L.
Journal of Polymer Research, 2022
.
Clathrochelates as components of new initiating systems for complex-radical polymerization of methyl methacrylate
Monakov Y.B., Islamova R.M., Sadykova G.R., Voloshin Y.Z., Makarenko I.G., Lebedev A.Y., Bubnov Y.N.
Doklady Chemistry, 2010
.
On the initial stage of the free-radical polymerizations of styrene and methyl methacrylate in the presence of fullerene C60
Yumagulova R.K., Kuznetsov S.I., Diniakhmetova D.R., Frizen A.K., Kraikin V.A., Kolesov S.V.
Kinetics and Catalysis, 2016
.
Regularities of postpolymerization in a vinyl monomer-metallocene-radical initiator system
Kolesov S.V., Nasibullin I.I., Frizen A.K., Sigaeva N.N., Galkin E.G.
Polymer Science - Series B, 2015
.
Novel carborane complexes of ruthenium with tridentate phosphine ligands: Synthesis and application in Atom Transfer Radical Polymerization
Kaltenberg A.A., Somov N.V., Malysheva Y.B., Knyazeva N.A., Piskunov A.V., Grishin I.D.
Journal of Organometallic Chemistry, 2020
.
Friesen A.K., Ulitin N.V., Khursan S.L., Shiyan D.A., Tereshchenko K.A., Kolesov S.V.
Mendeleev Communications, 2017
.
Katkova M.A., Zabrodina G.S., Rumyantcev R.V., Yu. Zhigulin G., Muravyeva M.S., Shurygina M.P., Chesnokov S.A., Yu. Ketkov S.
Mendeleev Communications, 2023
.
Suslov D.S., Suchkova A.V., Bykov M.V., Abramov Z.D., Pakhomova M.V., Orlov T.S., Ushakov I.A., Borodina T.N., Smirnov V.I.
Mendeleev Communications, 2023
.
Sadrtdinova G.I., Bardonov D.A., Lyssenko K.A., Minyaev M.E., Nifant'ev I.E., Roitershtein D.M.
Mendeleev Communications, 2023