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One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent

Lisha Ye 1
Lisha Ye
, 
Zhida Zhao 2
Zhida Zhao
, 
En-xue Lei 3
En-xue Lei
, 
Liang Wang 3
Liang Wang
1 Ningbo University of Finance and Economics, Zhejiang, P.R. China
2 Ningbo University of Technology, Zhejiang, P.R. China
3 School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
10.1016/j.mencom.2024.09.027
Published 2024-09-09
Communication , Volume 34, Issue 5, 709-710
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Ye L. et al. One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 709-710.
GOST all authors (up to 50) Copy
Ye L., Zhao Z., Lei E., Wang L. One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 709-710.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.027
TI - One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent
T2 - Mendeleev Communications
AU - Ye, Lisha
AU - Zhao, Zhida
AU - Lei, En-xue
AU - Wang, Liang
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 709-710
IS - 5
VL - 34
ER -
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@article{2024_Ye,
author = {Lisha Ye and Zhida Zhao and En-xue Lei and Liang Wang},
title = {One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.027},
number = {5},
pages = {709--710},
doi = {10.1016/j.mencom.2024.09.027}
}
MLA
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MLA Copy
Ye, Lisha, et al. “One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 709-710. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.027.

Keywords

aromatic aldehydes
arylacetylenes
deep eutectic solvent
one-pot synthesis.
sodium arenesulfinates
γ-keto sulfones

Abstract

Acidic deep eutectic solvent was prepared from choline chloride and trifluoromethanesulfonic acid at room temperature. Reaction between aromatic aldehydes and arylacetylenes in this solvent gave chalcones whose in situ reaction with sodium arenesulfinates in water successfully provided γ-keto sulfones in good yields. This deep eutectic solvent could be easily recovered and reused for several runs.

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