Home / Publications / New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes

New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes

Gulnara Nazifovna Kadikova 1
Gulnara Nazifovna Kadikova
, 
Ekaterina Sergeevna Meshcheryakova 1
Ekaterina Sergeevna Meshcheryakova
, 
Leonard Mukhibovich Khalilov 1
Leonard Mukhibovich Khalilov
1 Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
10.1016/j.mencom.2024.09.024
Published 2024-09-09
Communication , Volume 34, Issue 5, 701-702
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Kadikova G. N., Meshcheryakova E. S., Khalilov L. M. New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 701-702.
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Kadikova G. N., Meshcheryakova E. S., Khalilov L. M. New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 701-702.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.024
TI - New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes
T2 - Mendeleev Communications
AU - Kadikova, Gulnara Nazifovna
AU - Meshcheryakova, Ekaterina Sergeevna
AU - Khalilov, Leonard Mukhibovich
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 701-702
IS - 5
VL - 34
ER -
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@article{2024_Kadikova,
author = {Gulnara Nazifovna Kadikova and Ekaterina Sergeevna Meshcheryakova and Leonard Mukhibovich Khalilov},
title = {New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.024},
number = {5},
pages = {701--702},
doi = {10.1016/j.mencom.2024.09.024}
}
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Kadikova, Gulnara Nazifovna, et al. “New 4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones via the cycloaddition of N-phenylmaleimide and cyclohepta-1,3,5-trienes.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 701-702. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.024.

Keywords

[4 + 2] cycloaddition
10]dodec-11-ene-3
3
4-azatetracyclo[5.3.2.02
5-diones
5-trienes
6.08
7-substituted cyclohepta-1
biologically active compounds.
diene adducts
N-phenylmaleimide

Abstract

The cycloaddition reactions of N-phenylmaleimide with 7-substituted cyclohepta-1,3,5-trienes afforded new 4-aza- tetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-diones in high yields (87-97%). The true substrates which underwent the [4 + 2] cycloaddition were the 7-R-bicyclo[4.1.0]hepta-2,4-diene tautomers. The structures of the synthesized compounds were proved by NMR spectroscopy and X-ray diffraction analysis.

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