Keywords
Dioxadet
enthalpy
heat capacity.
hydration
solution
sublimation
Abstract
Thermochemical data on hydration of the well-established anticancer agent Dioxadet were obtained. Its enthalpies of solution and sublimation at various temperatures were determined calorimetrically, and on their basis the standard enthalpy (ΔhydrH0 = −154.6 ± 3.6 kJ mol−1) and the standard heat capacity (ΔhydrCp0 = 384 ± 80 J mol−1 K−1) of the transfer of the solute from the state of an ideal gas to an aqueous solution at infinite dilution at 298.15 K were calculated.
References
.
Krestyaninov M.A., Kustov A.V.
Mendeleev Communications,
2020
.
Gallagher K.R., Sharp K.A.
Journal of the American Chemical Society,
2003
.
.
Hallén D., Nilsson S.-., Wadsö I.
Journal of Chemical Thermodynamics,
1989
.
Ahrenberg M., Brinckmann M., Schmelzer J.W., Beck M., Schmidt C., Keßler O., Kragl U., Verevkin S.P., Schick C.
Physical Chemistry Chemical Physics,
2014
.
Madan B., Sharp K.
Journal of Physical Chemistry B,
1997
.
Chickos J.S., Hosseini S., Hesse D.G., Liebman J.F.
Structural Chemistry,
1993
.
Bespalov V.G., Alvovsky I.K., Tochilnikov G.V., Stukov A.N., Vyshinskaya E.A., Semenov A.L., Vasilyeva I.N., Belyaeva O.A., Kireeva G.S., Senchik K.Y., Zhilinskaya N.T., Von J.D., Krasilnikova L.A., Alexandrov V.A., Khromov-Borisov N.N., et. al.
International Journal of Hyperthermia,
2017
.
Zhikhoreva A.A., Belashov A.V., Bespalov V.G., Semenov A.L., Semenova I.V., Tochilnikov G.V., Zhilinskaya N.T., Vasyutinskii O.S.
Biomedical Optics Express,
2018
.
Kustov A.V., Antonova O.A., Smirnova N.L.
Journal of Thermal Analysis and Calorimetry,
2017
.
Acree W., Chickos J.S.
Journal of Physical and Chemical Reference Data,
2022
.
Buzyurov A.V., Nagrimanov R.N., Zaitsau D.H., Mukhametzyanov T.A., Abdelaziz A., Solomonov B.N., Schick C.
Thermochimica Acta,
2021
.
Cebe P., Thomas D., Merfeld J., Partlow B.P., Kaplan D.L., Alamo R.G., Wurm A., Zhuravlev E., Schick C.
Polymer,
2017
.
Madan B., Sharp K.
Biophysical Chemistry,
1999
.
Kustov A.V., Antonova O.A., Smirnova N.L., Kladiev A.A., Kladiev A.A., Kudayarova T.V., Gruzdev M.S., Berezin D.B.
Journal of Molecular Liquids,
2018
.
Kustov A.V., Kudayarova T.V., Antonova O.A., Smirnova N.L., Kladiev A.A., Kladiev A.A.
Mendeleev Communications,
2019
.
Ivanov E.V., Kustov A.V., Batov D.V., Smirnova N.L., Pechnikova N.L.
Journal of Molecular Liquids,
2020
.
Bespalov V.G., Kireeva G.S., Belyaeva O.A., Senchik K.Y., Stukov A.N., Maydin M.A., Semenov A.L., Gafton G.I., Guseynov K.D., Belyaev A.M.
Journal of Chemotherapy,
2016
.
Bolmatenkov D.N., Yagofarov M.I., Valiakhmetov T.F., Rodionov N.O., Solomonov B.N.
Journal of Chemical Thermodynamics,
2022