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Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids

Zakhar Mikhailovich Rubanov 1
Zakhar Mikhailovich Rubanov
, 
Mikhail Dmitrievich Kosobokov 1
Mikhail Dmitrievich Kosobokov
, 
Vitalij Vladimirovich Levin 1
Vitalij Vladimirovich Levin
, 
10.1016/j.mencom.2024.09.015
Published 2024-09-09
Communication , Volume 34, Issue 5, 673-675
3
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Rubanov Z. M. et al. Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 673-675.
GOST all authors (up to 50) Copy
Rubanov Z. M., Kosobokov M. D., Levin V. V., Dilman A. D. Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 673-675.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.015
TI - Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids
T2 - Mendeleev Communications
AU - Rubanov, Zakhar Mikhailovich
AU - Kosobokov, Mikhail Dmitrievich
AU - Levin, Vitalij Vladimirovich
AU - Dilman, Alexander Davidovich
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 673-675
IS - 5
VL - 34
ER -
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@article{2024_Rubanov,
author = {Zakhar Mikhailovich Rubanov and Mikhail Dmitrievich Kosobokov and Vitalij Vladimirovich Levin and Alexander Davidovich Dilman},
title = {Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.015},
number = {5},
pages = {673--675},
doi = {10.1016/j.mencom.2024.09.015}
}
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Cite this
MLA Copy
Rubanov, Zakhar Mikhailovich, et al. “Visible light-driven decarboxylative alkylation of azomethine imines with carboxylic acids.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 673-675. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.015.

Keywords

acridine catalysis
azomethine imines
carboxylic acids
decatungstate
photocatalysis
pyrazolidin-3-ones.
radical reactions

Abstract

The alkylation of cyclic five-membered azomethine imines with carboxylic acids proceeds under irradiation with 400 nm light using a dual catalytic system consisting of 9-arylacridine and tetrabutylammonium decatungstate. Azomethine imines containing aromatic, heterocyclic and aliphatic groups are suitable for the process providing pyrazolidin-3-ones in 42-98% yields.

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