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Novel dithieno[3,2-f:2',3'-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells

Ekaterina Andreevna Komissarova 1
Ekaterina Andreevna Komissarova
Sergei Alexandrovich Kuklin 1, 2
Sergei Alexandrovich Kuklin
Maria Nan'ovna Kevreva 1
Maria Nan'ovna Kevreva
Nikita Alexandrovich Emelianov
Lyubov' Anatol'evna Frolova 1
Lyubov' Anatol'evna Frolova
Pavel Anatol'evich Troshin
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
3 Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou, China
Published 2024-09-09
CommunicationVolume 34, Issue 5, 656-659
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Komissarova E. A. et al. Novel dithieno[3,2-f:2',3'-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 656-659.
GOST all authors (up to 50) Copy
Komissarova E. A., Kuklin S. A., Latypova A. F., Nikitenko S. L., Ozerova V. V., Kevreva M. N., Emelianov N. A., Frolova L. A., Troshin P. A. Novel dithieno[3,2-f:2',3'-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 656-659.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.010
TI - Novel dithieno[3,2-f:2',3'-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells
T2 - Mendeleev Communications
AU - Komissarova, Ekaterina Andreevna
AU - Kuklin, Sergei Alexandrovich
AU - Latypova, Alina Fidarisovna
AU - Nikitenko, Sergei Leonidovich
AU - Ozerova, Victoria Victorovna
AU - Kevreva, Maria Nan'ovna
AU - Emelianov, Nikita Alexandrovich
AU - Frolova, Lyubov' Anatol'evna
AU - Troshin, Pavel Anatol'evich
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 656-659
IS - 5
VL - 34
ER -
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@article{2024_Komissarova,
author = {Ekaterina Andreevna Komissarova and Sergei Alexandrovich Kuklin and Alina Fidarisovna Latypova and Sergei Leonidovich Nikitenko and Victoria Victorovna Ozerova and Maria Nan'ovna Kevreva and Nikita Alexandrovich Emelianov and Lyubov' Anatol'evna Frolova and Pavel Anatol'evich Troshin},
title = {Novel dithieno[3,2-f:2',3'-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.010},
number = {5},
pages = {656--659},
doi = {10.1016/j.mencom.2024.09.010}
}
MLA
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Komissarova, Ekaterina Andreevna, et al. “Novel dithieno[3,2-f:2',3'-h]quinoxaline-based polymers as hole transport materials for perovskite solar cells.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 656-659. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.010.

Keywords

1
2
2-f:2’
3-benzothiadiazole
3’-h]quinoxaline
dithieno[3
hole transport materials
perovskite solar cells
PSCs.
Stille cross-coupling

Abstract

Two novel conjugated polymers comprised of 2,3-R2-di- thieno[3,2-f:2’,3’-h]quinoxaline, where R is 3’-(octyloxy)- phenyl (P1) or 2’-(2-ethylhexyl)thiophen-4’-yl (P2), and 2,1,3-benzothiadiazole have been synthesized using the Stille cross-coupling reaction. The synthesized polymers were investigated as hole transport layer (HTL) materials in perovskite solar cells. Polymer P2 as an HTL material provided improved short-circuit current and open-circuit voltage and, correspondingly, enhanced power conversion efficiency of perovskite solar cells compared to that of polymer P1.

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