Home / Publications / Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode

Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode

Alexey Pavlovich Dovzhenko 1
Alexey Pavlovich Dovzhenko
Anna Andreevna Betina 2
Anna Andreevna Betina
Tatyana Sergeevna Bulatova 2
Tatyana Sergeevna Bulatova
Nikita Aleksandrovich Bogachev 2
Nikita Aleksandrovich Bogachev
Victor Gennad'evich Nikiforov 3
Victor Gennad'evich Nikiforov
Alexandra Dmitrievna Voloshina 1
Alexandra Dmitrievna Voloshina
Rustem Ravilevich Zairov 1, 4
Rustem Ravilevich Zairov
Andrey Sergeyevich Mereshchenko 2
Andrey Sergeyevich Mereshchenko
Bulat Salavatovich Akhmadeev
1 A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
2 Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation
3 E.K. Zavoisky Physical-Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
4 Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
Published 2024-09-09
CommunicationVolume 34, Issue 5, 637-639
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Dovzhenko A. P. et al. Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 637-639.
GOST all authors (up to 50) Copy
Dovzhenko A. P., Betina A. A., Bulatova T. S., Bogachev N. A., Nikiforov V. G., Voloshina A. D., Zairov R. R., Mustafina A. R., Mereshchenko A. S., Akhmadeev B. S. Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode // Mendeleev Communications. 2024. Vol. 34. No. 5. pp. 637-639.
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TY - JOUR
DO - 10.1016/j.mencom.2024.09.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.004
TI - Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode
T2 - Mendeleev Communications
AU - Dovzhenko, Alexey Pavlovich
AU - Betina, Anna Andreevna
AU - Bulatova, Tatyana Sergeevna
AU - Bogachev, Nikita Aleksandrovich
AU - Nikiforov, Victor Gennad'evich
AU - Voloshina, Alexandra Dmitrievna
AU - Zairov, Rustem Ravilevich
AU - Mustafina, Asiya Rafaelevna
AU - Mereshchenko, Andrey Sergeyevich
AU - Akhmadeev, Bulat Salavatovich
PY - 2024
DA - 2024/09/09
PB - Mendeleev Communications
SP - 637-639
IS - 5
VL - 34
ER -
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@article{2024_Dovzhenko,
author = {Alexey Pavlovich Dovzhenko and Anna Andreevna Betina and Tatyana Sergeevna Bulatova and Nikita Aleksandrovich Bogachev and Victor Gennad'evich Nikiforov and Alexandra Dmitrievna Voloshina and Rustem Ravilevich Zairov and Asiya Rafaelevna Mustafina and Andrey Sergeyevich Mereshchenko and Bulat Salavatovich Akhmadeev},
title = {Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.004},
number = {5},
pages = {637--639},
doi = {10.1016/j.mencom.2024.09.004}
}
MLA
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Dovzhenko, Alexey Pavlovich, et al. “Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode.” Mendeleev Communications, vol. 34, no. 5, Sep. 2024, pp. 637-639. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.09.004.

Keywords

cell internalization
contrast agent
Eu-based luminescence.
fluorescent imaging
fluoride nanoparticle
hydrophilic coating
polymer

Abstract

This work introduces non-covalent hydrophilic coating of NaGd0.7Eu0.3F4 nanocrystals by polylysine (PL) and polyethyleneimine (PEI) for MRI and fluorescent imaging purposes. PL- and PEI-stabilized nanocrystals exhibit high colloidal stability, cell internalization, fluorescent contrasting of nuclei and cytoplasm, low cytotoxicity, and relaxivity (r1= 0.17 dm3 mmol-1 s-1 and r1 = 0.23 dm3 mmol-1 s-1).

References

.
Gadolinium(III) Chelates as MRI Contrast Agents:  Structure, Dynamics, and Applications
Caravan P., Ellison J.J., McMurry T.J., Lauffer R.B.
Chemical Reviews, 1999
.
Size-Tunable, Ultrasmall NaGdF4 Nanoparticles: Insights into Their T1 MRI Contrast Enhancement
Johnson N.J., Oakden W., Stanisz G.J., Scott Prosser R., van Veggel F.C.
Chemistry of Materials, 2011
.
Polymer-Stabilized Lanthanide Fluoride Nanoparticle Aggregates as Contrast Agents for Magnetic Resonance Imaging and Computed Tomography
Cheung E.N., Alvares R.D., Oakden W., Chaudhary R., Hill M.L., Pichaandi J., Mo G.C., Yip C., Macdonald P.M., Stanisz G.J., van Veggel F.C., Prosser R.S.
Chemistry of Materials, 2010
.
Molecular and Nano-Structural Optimization of Nanoparticulate Mn2+-Hexarhenium Cluster Complexes for Optimal Balance of High T1- and T2-Weighted Contrast Ability with Low Hemoagglutination and Cytotoxicity
Akhmadeev B.S., Nizameev I.R., Kholin K.V., Voloshina A.D., Gerasimova T.P., Gubaidullin A.T., Kadirov M.K., Ismaev I.E., Brylev K.A., Zairov R.R., Mustafina A.R.
Pharmaceutics, 2022
.
Lanthanide-Ion-Doping Effect on the Morphology and the Structure of NaYF4:Ln3+ Nanoparticles
Bogachev N.A., Betina A.A., Bulatova T.S., Nosov V.G., Kolesnik S.S., Tumkin I.I., Ryazantsev M.N., Skripkin M.Y., Mereshchenko A.S.
Nanomaterials, 2022
.
Synthesis and Characterization of PEGylated Gd2O3 Nanoparticles for MRI Contrast Enhancement
Ahrén M., Selegård L., Klasson A., Söderlind F., Abrikossova N., Skoglund C., Bengtsson T., Engström M., Käll P., Uvdal K.
Langmuir, 2010
.
Multifunctional Liposome Nanocarriers Combining Upconverting Nanoparticles and Anticancer Drugs
Huang Y., Hemmer E., Rosei F., Vetrone F.
Journal of Physical Chemistry B, 2016
.
Renal-clearable hyaluronic acid functionalized NaGdF4nanodots with enhanced tumor accumulation
Yan Y., Ding L., Liu L., Abualrejal M.M., Chen H., Wang Z.
RSC Advances, 2020
.
The effect of Eu3+ and Gd3+ co-doping on the morphology and luminescence of NaYF4:Eu3+, Gd3+ phosphors
Kolesnikov I.E., Vidyakina A.A., Vasileva M.S., Nosov V.G., Bogachev N.A., Sosnovsky V.B., Skripkin M.Y., Tumkin I.I., Lähderanta E., Mereshchenko A.S.
New Journal of Chemistry, 2021
.
NaGdF4:Yb,Er-Ag nanowire hybrid nanocomposite for multifunctional upconversion emission, optical imaging, MRI and CT imaging applications
Yamini S., Gunaseelan M., Kumar G.A., Singh S., Dannangoda G.C., Martirosyan K.S., Sardar D.K., Sivakumar S., Girigoswami A., Senthilselvan J.
Microchimica Acta, 2020
.
Cytotoxic interactions of bare and coated NaGdF4:Yb3+:Er3+ nanoparticles with macrophage and fibroblast cells
Wysokińska E., Cichos J., Zioło E., Bednarkiewicz A., Strządała L., Karbowiak M., Hreniak D., Kałas W.
Toxicology in Vitro, 2016
.
Cytotoxicity of polyethyleneimine (PEI), precursor base layer of polyelectrolyte multilayer films
Brunot C., Ponsonnet L., Lagneau C., Farge P., Picart C., Grosgogeat B.
Biomaterials, 2007
.
Bioorthogonal Paramagnetic Nanocrystalline Phosphor NaGd0.7Eu0.3F4
Bulatova T.S., Bogachev N.A., Betina A.A., Smirnov A.N., Solovieva E.V., Skripkin M.Y., Mereshchenko A.S.
Russian Journal of General Chemistry, 2022
.
Enhancing upconversion via constructing local energy cluster in lanthanide doped fluoride nanoparticles
Yang H., Zhang A., Guo H., Li D., Xu S., Lei L.
Journal of Materials Chemistry C, 2023