Keywords
crazing
crystallization of polymers
high-density polyethylene
mesoporous polymers
nanocomposites.
poly(vinyl alcohol)
Abstract
Poly(vinyl alcohol) (PVA) was incorporated into the mesoporous structure of high-density polyethylene (HDPE) directly upon the tensile drawing of films via crazing in water-ethanol PVA solutions. The structure and thermophysical properties of the HDPE-PVA nanocomposites were explored by differential scanning calorimetry and X-ray analysis. PVA was found to exist in an amorphized state within the mesoporous structure of the HDPE host matrix since its crystallization is prevented by the spatial confinements.
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