Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability

Valeeva, Al'bina Ahmetovna; Gerasimov, Evgeny Yur'evich; Reznitskikh, Olga Grigor'evna

doi:10.1016/j.mencom.2024.06.043

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Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability

Al'bina Ahmetovna Valeeva ¹

Al'bina Ahmetovna Valeeva

,

Evgeny Yur'evich Gerasimov ²

Evgeny Yur'evich Gerasimov

,

Olga Grigor'evna Reznitskikh ¹

Olga Grigor'evna Reznitskikh

¹ Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

² G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

10.1016/j.mencom.2024.06.043

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Published 2024-06-19

Communication , Volume 34, Issue 4, 601-603

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Valeeva A. A., Gerasimov E. Y., Reznitskikh O. G. Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 601-603.

GOST all authors (up to 50) Copy

Valeeva A. A., Gerasimov E. Y., Reznitskikh O. G. Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 601-603.

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TY - JOUR

DO - 10.1016/j.mencom.2024.06.043

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.043

TI - Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability

T2 - Mendeleev Communications

AU - Valeeva, Al'bina Ahmetovna

AU - Gerasimov, Evgeny Yur'evich

AU - Reznitskikh, Olga Grigor'evna

PY - 2024

DA - 2024/06/19

PB - Mendeleev Communications

SP - 601-603

IS - 4

VL - 34

ER -

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@article{2024_Valeeva,

author = {Al'bina Ahmetovna Valeeva and Evgeny Yur'evich Gerasimov and Olga Grigor'evna Reznitskikh},

title = {Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability},

journal = {Mendeleev Communications},

year = {2024},

volume = {34},

publisher = {Mendeleev Communications},

month = {Jun},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.043},

number = {4},

pages = {601--603},

doi = {10.1016/j.mencom.2024.06.043}

}

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Valeeva, Al'bina Ahmetovna, et al. “Effect of particle size of titanium oxide β-Ti3O5 on its thermal stability.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 601-603. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.043.

Keywords

DSC.

nanocrystal

SEM

TEM

TG

Ti3O5

titanium oxide

XRD

Abstract

It was established that the particle size of titanium oxide β-Ti3O5 has a great influence on the processes of phase formation and the stability of particles during heating. It was shown that at a temperature of about 456 K, β-Ti3O5 micro crystals undergo a reversible first-order phase transition, in which the low- temperature β-Ti3O5 phase is transformed into the high-temperature λ- Ti3O5 phase, and at higher temperatures the β-Ti3O5 phase is partially oxidized to form the Magneli phase Ti4O7. It was found that β-Ti3O5 nanocrystals are unstable in an argon atmosphere and at temperatures above 400 K the β-Ti3O5 powder is oxidized.

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