NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas

Zagaynov, Igor Valer'evich; Loktev, Alexey Sergeevich; Konovalov, Anatoly Anatol'evich; Klimashin, Anton Alekseevich; Antonova, Olga Stanislavovna; Dedov, Alexey Georgievich

doi:10.1016/j.mencom.2024.06.034

Home / Publications / NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas

NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas

Igor Valer'evich Zagaynov ¹

Igor Valer'evich Zagaynov

,

Alexey Sergeevich Loktev ²

Alexey Sergeevich Loktev

,

Anatoly Anatol'evich Konovalov ¹

Anatoly Anatol'evich Konovalov

,

Anton Alekseevich Klimashin ¹

Anton Alekseevich Klimashin

,

Olga Stanislavovna Antonova ¹

Olga Stanislavovna Antonova

,

Alexey Georgievich Dedov ^{2, 3}

Alexey Georgievich Dedov

¹ A. A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow, Russian Federation

² A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

³ National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation

10.1016/j.mencom.2024.06.034

Copy DOI

Published 2024-06-19

Communication , Volume 34, Issue 4, 572-575

View PDF

Supporting information

Graphical abstract

1

Share

Cite this

GOST

|

Cite this

GOST Copy

Zagaynov I. V. et al. NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 572-575.

GOST all authors (up to 50) Copy

Zagaynov I. V., Loktev A. S., Konovalov A. A., Klimashin A. A., Antonova O. S., Dedov A. G. NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 572-575.

RIS

|

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2024.06.034

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.034

TI - NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas

T2 - Mendeleev Communications

AU - Zagaynov, Igor Valer'evich

AU - Loktev, Alexey Sergeevich

AU - Konovalov, Anatoly Anatol'evich

AU - Klimashin, Anton Alekseevich

AU - Antonova, Olga Stanislavovna

AU - Dedov, Alexey Georgievich

PY - 2024

DA - 2024/06/19

PB - Mendeleev Communications

SP - 572-575

IS - 4

VL - 34

ER -

BibTex

|

Cite this

BibTex (up to 50 authors) Copy

@article{2024_Zagaynov,

author = {Igor Valer'evich Zagaynov and Alexey Sergeevich Loktev and Anatoly Anatol'evich Konovalov and Anton Alekseevich Klimashin and Olga Stanislavovna Antonova and Alexey Georgievich Dedov},

title = {NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas},

journal = {Mendeleev Communications},

year = {2024},

volume = {34},

publisher = {Mendeleev Communications},

month = {Jun},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.034},

number = {4},

pages = {572--575},

doi = {10.1016/j.mencom.2024.06.034}

}

MLA

Cite this

MLA Copy

Zagaynov, Igor Valer'evich, et al. “NiCo-Gd0.1Ti0.1Zr0.1Ce0.7O2 catalyst for dry reforming and partial oxidation of methane: effect of NiCo applying method on the conversion of methane to synthesis gas.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 572-575. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.034.

Keywords

ceria

dry reforming of methane

effect of preparation

NiCo

partial oxidation of methane

syngas.

Abstract

A series of catalysts based on mesoporous ceria solid solutions containing NiCo active component was synthesized via co- precipitation, impregnation, hydrothermal and core-shell (sol-gel) methods and applied to partial oxidation and dry reforming of methane. In the co-precipitated and impregnated catalysts, a better NiCo dispersion and a stronger interaction between NiCo species and the ceria- based support in comparison with other catalysts were observed, which affected activity and selectivity. Thus, simpler methods of applying the active component were more advantageous owing to the manifestation of strong metal-support interactions.

References

.

10.1021/acs.chemrev.5b00603

Fundamentals and Catalytic Applications of CeO2-Based Materials

Montini T., Melchionna M., Monai M., Fornasiero P.

Chemical Reviews, 2016

.

10.1016/j.mencom.2022.01.042

Effect of the oxidizing capacity of ceria-based support on the conversion of methane to syngas

Zagaynov I.V., Loktev A.S., Mukhin I.E., Konovalov A.A., Dedov A.G.

Mendeleev Communications, 2022

.

10.1016/j.cej.2016.01.066

Ni(Co)–Gd 0.1 Ti 0.1 Zr 0.1 Ce 0.7 O 2 mesoporous materials in partial oxidation and dry reforming of methane into synthesis gas

Zagaynov I.V., Loktev A.S., Arashanova A.L., Ivanov V.K., Dedov A.G., Moiseev I.I.

Chemical Engineering Journal, 2016

.

10.1016/j.mencom.2017.09.027

Influence of the Ni/Co ratio in bimetallic NiCo catalysts on methane conversion into synthesis gas

Zagaynov I.V., Loktev A.S., Mukhin I.E., Dedov A.G., Moiseev I.I.

Mendeleev Communications, 2017

.

10.1016/j.cocis.2007.10.001

Recent developments in the application of nanoparticles prepared from w/o microemulsions in heterogeneous catalysis

Boutonnet M., Lögdberg S., Elm Svensson E.

Current Opinion in Colloid and Interface Science, 2008

.

10.1016/j.apcata.2008.05.018

A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts

Christian Enger B., Lødeng R., Holmen A.

Applied Catalysis A: General, 2008

.

10.1142/p717

Concepts in Syngas Manufacture

Rostrup-Nielsen J., Christiansen L.J.

Catalytic Science Series, 2011

.

10.1016/j.apcata.2015.07.040

Effect of Co/Ni ratios in cobalt nickel mixed oxide catalysts on methane combustion

Lim T.H., Cho S.J., Yang H.S., Engelhard M.H., Kim D.H.

Applied Catalysis A: General, 2015

.

10.1016/j.apcatb.2015.05.013

Dry reforming of methane over CeO2 supported Ni, Co and Ni–Co catalysts

Ay H., Üner D.

Applied Catalysis B: Environmental, 2015

.

10.1016/j.ijhydene.2009.06.038

Biogas reforming for hydrogen production over nickel and cobalt bimetallic catalysts

Xu J., Zhou W., Li Z., Wang J., Ma J.

International Journal of Hydrogen Energy, 2009

.

10.1021/ef101479y

Influence of the Catalyst Preparation Method, Surfactant Amount, and Steam on CO₂ Reforming of CH₄ over 5Ni/Ce_0.6Zr_0.4O₂ Catalysts

Sukonket T., Khan A., Saha B., Ibrahim H., Tantayanon S., Kumar P., Idem R.

Energy & Fuels, 2011

.

10.1021/jacs.8b10910

Synergy of Single-Atom Ni₁ and Ru₁ Sites on CeO₂ for Dry Reforming of CH₄

Tang Y., Wei Y., Wang Z., Zhang S., Li Y., Nguyen L., Li Y., Zhou Y., Shen W., Tao F.F., Hu P.

Journal of the American Chemical Society, 2019

.

10.1021/acs.jpcc.9b09856

Critical Role of Interfacial Sites between Nickel and CeO₂ Support in Dry Reforming of Methane: Revisit of Reaction Mechanism and Origin of Stability

Lian Z., Olanrele S.O., Si C., Yang M., Li B.

Journal of Physical Chemistry C, 2020

.

10.1021/acs.jpcc.9b10190

Insight into Size- and Metal-Dependent Activity and the Mechanism for Steam Methane Re-forming in Nanocatalysis

Wang Y., Xiao L., Qi Y., Yang J., Zhu Y., Chen D.

Journal of Physical Chemistry C, 2020

.

10.1021/acs.energyfuels.1c00219

Active Components of Catalysts of Methane Conversion to Synthesis Gas: Brief Perspectives

Zagaynov I.V.

Energy & Fuels, 2021

.

10.1021/acs.iecr.2c01915

Syngas Production via Combined Steam and Carbon Dioxide Reforming of Methane over Ni-Ce_xM_1–xO₂ (M = Ti or Zr) Catalysts

Zhao Y., Qi L., Cheng Z., Zhou Z.

Industrial & Engineering Chemistry Research, 2022

.

10.1134/s0023158409010182

Catalytic activity and physicochemical properties of Ni-Au/Al3CrO6 system for partial oxidation of methane to synthesis gas

Maniecki T.P., Bawolak K., Gebauer D., Mierczynski P., Jozwiak W.K.

Kinetics and Catalysis, 2009

.

10.1016/j.apcatb.2021.120321

Dry reforming of methane over Ni/Ce0.8Ti0.2O2-δ: The effect of Ni particle size on the carbon pathways studied by transient and isotopic techniques

Damaskinos C.M., Zavašnik J., Djinović P., Efstathiou A.M.

Applied Catalysis B: Environmental, 2021

.

10.1016/j.apcatb.2021.120454

Interfacial synergistic catalysis over Ni nanoparticles encapsulated in mesoporous ceria for CO2 methanation

Hongmanorom P., Ashok J., Chirawatkul P., Kawi S.

Applied Catalysis B: Environmental, 2021

.

10.1016/j.apcatb.2020.119445

In situ auto-gasification of coke deposits over a novel Ni-Ce/W-Zr catalyst by sequential generation of oxygen vacancies for remarkably stable syngas production via CO2-reforming of methane

Al-Fatesh A.S., Arafat Y., Kasim S.O., Ibrahim A.A., Abasaeed A.E., Fakeeha A.H.

Applied Catalysis B: Environmental, 2021

.

10.1016/j.rser.2015.02.026

Dry reforming of methane: Influence of process parameters—A review

Usman M., Wan Daud W.M., Abbas H.F.

Renewable and Sustainable Energy Reviews, 2015

.

10.1016/j.apcata.2015.05.004

Ni/CeO2–Al2O3 catalysts for the dry reforming of methane: The effect of CeAlO3 content and nickel crystallite size on catalytic activity and coke resistance

Luisetto I., Tuti S., Battocchio C., Lo Mastro S., Sodo A.

Applied Catalysis A: General, 2015

.

10.1016/j.ceramint.2015.03.093

Sonochemical synthesis of mesoporous Gd Zr Ti Ce1−––O2 solid solution

Zagaynov I.V.

Ceramics International, 2015

.

10.1016/j.apcatb.2015.05.021

Low temperature dry reforming of methane over Pt–Ni–Mg/ceria–zirconia catalysts

Elsayed N.H., Roberts N.R., Joseph B., Kuhn J.N.

Applied Catalysis B: Environmental, 2015

.

10.1016/j.apcatb.2017.04.076

In-operando elucidation of bimetallic CoNi nanoparticles during high-temperature CH4/CO2 reaction

AlSabban B., Falivene L., Kozlov S.M., Aguilar-Tapia A., Ould-Chikh S., Hazemann J., Cavallo L., Basset J., Takanabe K.

Applied Catalysis B: Environmental, 2017

.

10.1016/j.apcata.2018.01.033

Bimetallic Ni-Co/SBA-15 catalysts prepared by urea co-precipitation for dry reforming of methane

Xin J., Cui H., Cheng Z., Zhou Z.

Applied Catalysis A: General, 2018

.

10.1016/j.catcom.2012.11.008

Metal–support interface of a novel Ni–CeO2 catalyst for dry reforming of methane

Odedairo T., Chen J., Zhu Z.

Catalysis Communications, 2013

.

10.1016/j.apcata.2012.10.037

Carbon dioxide reforming of methane to synthesis gas over a TiO2–Ni inverse catalyst

Seo H.O., Sim J.K., Kim K., Kim Y.D., Lim D.C., Kim S.H.

Applied Catalysis A: General, 2013

.

10.1016/j.ijhydene.2013.08.026

The effect of preparation method on the catalytic performance over superior MgO-promoted Ni–Ce0.8Zr0.2O2 catalyst for CO2 reforming of CH4

Jeong D., Jang W., Shim J., Roh H., Son I.H., Lee S.J.

International Journal of Hydrogen Energy, 2013

.

10.1016/j.mencom.2019.01.006

Trimetallic NiCoM catalysts (M = Mn, Fe, Cu) for methane conversion into synthesis gas

Zagaynov I.V., Loktev A.S., Mukhin I.E., Konovalov A.A., Dedov A.G., Moiseev I.I.

Mendeleev Communications, 2019

.

10.1016/j.ijhydene.2012.09.128

Mesoporous nanocrystalline ceria–zirconia solid solutions supported nickel based catalysts for CO2 reforming of CH4

Xu L., Song H., Chou L.

International Journal of Hydrogen Energy, 2012

.

10.1016/j.ijhydene.2010.11.042

Effect of Co–Ni ratio on the activity and stability of Co–Ni bimetallic aerogel catalyst for methane Oxy-CO2 reforming

Chen L., Zhu Q., Wu R.

International Journal of Hydrogen Energy, 2011

.

10.1016/j.cej.2010.11.045

Preparation of supported Ni catalysts on various metal oxides with core/shell structures and their tests for the steam reforming of methane

Kim H., Kang K., Kwak H., Kim J.H.

Chemical Engineering Journal, 2011

.

10.1016/j.apcatb.2020.119581

Highly active Ni/CeO2 catalyst for CO2 methanation: Preparation and characterization

Rui N., Zhang X., Zhang F., Liu Z., Cao X., Xie Z., Zou R., Senanayake S.D., Yang Y., Rodriguez J.A., Liu C.

Applied Catalysis B: Environmental, 2021

.

10.1016/j.fuel.2008.04.015

Effect of preparation methods on structure and performance of Ni/Ce0.75Zr0.25O2 catalysts for CH4–CO2 reforming

CHEN J., WU Q., ZHANG J., ZHANG J.

Fuel, 2008

.

10.1016/j.ces.2021.116606

Recent progress in ceria-based catalysts for the dry reforming of methane: A review

Teh L.P., Setiabudi H.D., Timmiati S.N., Aziz M.A., Annuar N.H., Ruslan N.N.

Chemical Engineering Science, 2021

.

10.1007/s10562-023-04454-4

Hydrogen Production from Methane with CO2 Utilization over Exsolution Derived Bimetallic NiCu/CeO2 Catalysts

Matus E.V., Sukhova O.B., Kerzhentsev M.A., Ismagilov I.Z., Yashnik S.A., Ushakov V.A., Larina T.V., Gerasimov E.Y., Stonkus O.A., Nikitin A.P., Li L., Ismagilov Z.R.

Catalysis Letters, 2023

.

10.57634/RCR5079

Single-atom catalysts in methane chemistry

Kolesnichenko Natalia V., Ezhova Nataliya N., Snatenkova Yulia M.

Russian Chemical Reviews, 2023