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Thia-Michael addition in a Bronsted acidic deep eutectic solvent

Ya-Juan Fan 1
Ya-Juan Fan
, 
Dan Wang 1
Dan Wang
, 
Liang Wang 1
Liang Wang
, 
Yongsheng Zhou 2
Yongsheng Zhou
1 School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
2 School of Petrochemical Engineering, Changzhou University, Changzhou, China
10.1016/j.mencom.2024.06.030
Published 2024-06-19
Communication , Volume 34, Issue 4, 561-562
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Fan Y. et al. Thia-Michael addition in a Bronsted acidic deep eutectic solvent // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 561-562.
GOST all authors (up to 50) Copy
Fan Y., Wang D., Wang L., Zhou Y. Thia-Michael addition in a Bronsted acidic deep eutectic solvent // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 561-562.
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TY - JOUR
DO - 10.1016/j.mencom.2024.06.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.030
TI - Thia-Michael addition in a Bronsted acidic deep eutectic solvent
T2 - Mendeleev Communications
AU - Fan, Ya-Juan
AU - Wang, Dan
AU - Wang, Liang
AU - Zhou, Yongsheng
PY - 2024
DA - 2024/06/19
PB - Mendeleev Communications
SP - 561-562
IS - 4
VL - 34
ER -
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@article{2024_Fan,
author = {Ya-Juan Fan and Dan Wang and Liang Wang and Yongsheng Zhou},
title = {Thia-Michael addition in a Bronsted acidic deep eutectic solvent},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.030},
number = {4},
pages = {561--562},
doi = {10.1016/j.mencom.2024.06.030}
}
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Fan, Ya-Juan, et al. “Thia-Michael addition in a Bronsted acidic deep eutectic solvent.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 561-562. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.030.

Keywords

atom economy
C–S bond formation
deep eutectic solvent
green chemistry.
sulfides
thia-Michael addition
α
β-unsaturated carbonyl compounds

Abstract

A 100% atom-efficient thia-Michael addition process between thiols and α,β -unsaturated carbonyl compounds in a Bronsted acidic deep eutectic solvent at room temperature has been developed. The medium, choline chloride/p-toluene- sulfonic acid, not only showed good catalytic activity, but also could be readily recovered and reused with slight decrease in its activity after successive five runs.

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