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Cyclization of adiponitrile in the reaction with diphenylzirconocene

Maxim Vladimirovich Andreev 1
Maxim Vladimirovich Andreev
,  , 
Vyacheslav Sergeevich Bogdanov 1
Vyacheslav Sergeevich Bogdanov
, 
Alexander Fedorovich Smol'yakov 1, 3
Alexander Fedorovich Smol'yakov
, 
Vladimir Vasil'evich Burlakov 1
Vladimir Vasil'evich Burlakov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
3 G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
10.1016/j.mencom.2024.06.026
Published 2024-06-19
Communication , Volume 34, Issue 4, 550-551
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Andreev M. V. et al. Cyclization of adiponitrile in the reaction with diphenylzirconocene // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 550-551.
GOST all authors (up to 50) Copy
Andreev M. V., Akishkina I. A., Bogdanov V. S., Smol'yakov A. F., Burlakov V. V. Cyclization of adiponitrile in the reaction with diphenylzirconocene // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 550-551.
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TY - JOUR
DO - 10.1016/j.mencom.2024.06.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.026
TI - Cyclization of adiponitrile in the reaction with diphenylzirconocene
T2 - Mendeleev Communications
AU - Andreev, Maxim Vladimirovich
AU - Akishkina, Iuliia A
AU - Bogdanov, Vyacheslav Sergeevich
AU - Smol'yakov, Alexander Fedorovich
AU - Burlakov, Vladimir Vasil'evich
PY - 2024
DA - 2024/06/19
PB - Mendeleev Communications
SP - 550-551
IS - 4
VL - 34
ER -
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@article{2024_Andreev,
author = {Maxim Vladimirovich Andreev and Iuliia A Akishkina and Vyacheslav Sergeevich Bogdanov and Alexander Fedorovich Smol'yakov and Vladimir Vasil'evich Burlakov},
title = {Cyclization of adiponitrile in the reaction with diphenylzirconocene},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.026},
number = {4},
pages = {550--551},
doi = {10.1016/j.mencom.2024.06.026}
}
MLA
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MLA Copy
Andreev, Maxim Vladimirovich, et al. “Cyclization of adiponitrile in the reaction with diphenylzirconocene.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 550-551. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.026.

Keywords

adiponitrile
amidinate
amidines
azepines.
Cyclization
zirconium

Abstract

Intramolecular cyclization of adiponitrile with the formation of an amidinate functional group in zirconium coordination sphere was found. The obtained complex can be protolyzed with HCl in dioxane to afford a new representative of amidines, namely, 7-phenyl-1,3,4,5-tetrahydro-2H-azepin-2- imine in hydrochloride form.

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