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Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate-phenylacetate complex of terbium

Natalia Vyacheslavovna Gogoleva 1
Natalia Vyacheslavovna Gogoleva
, 
Maxim Andreevich Shmelev 1
Maxim Andreevich Shmelev
, 
Aleksandr Sergeevich Chistyakov 1
Aleksandr Sergeevich Chistyakov
, 
Galina Aleksandrovna Razgonyaeva 1
Galina Aleksandrovna Razgonyaeva
, 
Vladislav Mikailovich Korshunov 2
Vladislav Mikailovich Korshunov
,  , 
Il'ya Viktorovich Taidakov 2
Il'ya Viktorovich Taidakov
, 
Alexey Anatol'evich Sidorov 1
Alexey Anatol'evich Sidorov
, 
2 P.N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2024.06.005
Published 2024-06-19
Communication , Volume 34, Issue 4, 484-487
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Gogoleva N. V. et al. Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate-phenylacetate complex of terbium // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 484-487.
GOST all authors (up to 50) Copy
Gogoleva N. V., Shmelev M. A., Chistyakov A. S., Razgonyaeva G. A., Korshunov V. M., Tsorieva A. V., Taidakov I. V., Sidorov A. A., Eremenko I. L. Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate-phenylacetate complex of terbium // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 484-487.
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TY - JOUR
DO - 10.1016/j.mencom.2024.06.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.005
TI - Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate-phenylacetate complex of terbium
T2 - Mendeleev Communications
AU - Gogoleva, Natalia Vyacheslavovna
AU - Shmelev, Maxim Andreevich
AU - Chistyakov, Aleksandr Sergeevich
AU - Razgonyaeva, Galina Aleksandrovna
AU - Korshunov, Vladislav Mikailovich
AU - Tsorieva, Alisia Valer'evna
AU - Taidakov, Il'ya Viktorovich
AU - Sidorov, Alexey Anatol'evich
AU - Eremenko, Igor Leonidovich
PY - 2024
DA - 2024/06/19
PB - Mendeleev Communications
SP - 484-487
IS - 4
VL - 34
ER -
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@article{2024_Gogoleva,
author = {Natalia Vyacheslavovna Gogoleva and Maxim Andreevich Shmelev and Aleksandr Sergeevich Chistyakov and Galina Aleksandrovna Razgonyaeva and Vladislav Mikailovich Korshunov and Alisia Valer'evna Tsorieva and Il'ya Viktorovich Taidakov and Alexey Anatol'evich Sidorov and Igor Leonidovich Eremenko},
title = {Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate-phenylacetate complex of terbium},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.005},
number = {4},
pages = {484--487},
doi = {10.1016/j.mencom.2024.06.005}
}
MLA
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Gogoleva, Natalia Vyacheslavovna, et al. “Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate-phenylacetate complex of terbium.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 484-487. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.005.

Keywords

Hirshfeld surface analysis
mixed carboxylate complexes
non-covalent interactions
photoluminescence.
Terbium3+
X-ray structure

Abstract

A complex of mixed carboxylate pentafluorobenzoate (pfb) and phenylacetate (PhAc), viz. [Tb2(phen)2(pfb)2(PhAc)4] (phen is 1,10-phenanthroline), where each rare earth element (REE) ion is simultaneously coordinated to pentafluorobenzoic and phenylacetic acid anions, was for the first time synthesized and structurally characterized. To evaluate the influence of the second type of anion on the structure and photoluminescent properties, compounds with phenylacetic acid anions [Tb2(phen)2(PhAc)6] and pentafluorobenzoic acid anions [Tb2(EtOH)2(phen)2(pfb)6] were obtained. A change in the composition of the compounds from the phenylacetic acid anion to pentafluorobenzoate led to a change in the geometry of the metal scaffold and the REE polyhedron, a rearrangement of the system of non-covalent interactions according to the Hirshfeld surface analysis, and enhanced luminescence.

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