Home / Publications / Composite cathode material based on sulfur and microporous carbon for Li-S batteries

Composite cathode material based on sulfur and microporous carbon for Li-S batteries

Svetlana Aleksandrovna Novikova 1
Svetlana Aleksandrovna Novikova
Daria Yur'evna Voropaeva 1
Daria Yur'evna Voropaeva
Tatiana L'vovna Kulova 2
Tatiana L'vovna Kulova
Alexandr Mordukhaevich Skundin
Andrei Borisovich Yaroslavtsev 1
Andrei Borisovich Yaroslavtsev
2 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
Published 2024-06-19
CommunicationVolume 34, Issue 4, 478-480
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Novikova S. A. et al. Composite cathode material based on sulfur and microporous carbon for Li-S batteries // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 478-480.
GOST all authors (up to 50) Copy
Novikova S. A., Voropaeva D. Y., Li S. A., Kulova T. L., Skundin A. M., Stenina I. A., Yaroslavtsev A. B. Composite cathode material based on sulfur and microporous carbon for Li-S batteries // Mendeleev Communications. 2024. Vol. 34. No. 4. pp. 478-480.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2024.06.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.003
TI - Composite cathode material based on sulfur and microporous carbon for Li-S batteries
T2 - Mendeleev Communications
AU - Novikova, Svetlana Aleksandrovna
AU - Voropaeva, Daria Yur'evna
AU - Li, Sergey Andreevich
AU - Kulova, Tatiana L'vovna
AU - Skundin, Alexandr Mordukhaevich
AU - Stenina, Irina Alexandrovna
AU - Yaroslavtsev, Andrei Borisovich
PY - 2024
DA - 2024/06/19
PB - Mendeleev Communications
SP - 478-480
IS - 4
VL - 34
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Novikova,
author = {Svetlana Aleksandrovna Novikova and Daria Yur'evna Voropaeva and Sergey Andreevich Li and Tatiana L'vovna Kulova and Alexandr Mordukhaevich Skundin and Irina Alexandrovna Stenina and Andrei Borisovich Yaroslavtsev},
title = {Composite cathode material based on sulfur and microporous carbon for Li-S batteries},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.003},
number = {4},
pages = {478--480},
doi = {10.1016/j.mencom.2024.06.003}
}
MLA
Cite this
MLA Copy
Novikova, Svetlana Aleksandrovna, et al. “Composite cathode material based on sulfur and microporous carbon for Li-S batteries.” Mendeleev Communications, vol. 34, no. 4, Jun. 2024, pp. 478-480. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.06.003.

Keywords

adsorption
cathode material
Li–S battery
lithium polysulfides.
microporous carbon
sulfur

Abstract

In this work, a new cathode material for lithium-sulfur (Li-S) batteries was developed. Microporous carbon (with predominant pore size £1.2 nm) served as both a matrix for sulfur retention and conductive additive. Microporous carbon was shown to be capable of adsorbing lithium polysulfides thereby suppressing their migration toward lithium anode. The discharge capacity of the S/C composite at the 1st and 20th cycles in Li-S battery operation was 513 and 421 mAh g-1 at a scan rate of 0.1 mV s-1.

References

.
Voropaeva D.Y., Safronova E.Y., Novikova S.A., Yaroslavtsev A.B.
Mendeleev Communications, 2022
.
Elemental sulfur
Meyer B.
Chemical Reviews, 1976
.
Observation of Raman band shifting with excitation wavelength for carbons and graphites
Vidano R.P., Fischbach D.B., Willis L.J., Loehr T.M.
Solid State Communications, 1981
.
Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
Ji L., Rao M., Zheng H., Zhang L., Li Y., Duan W., Guo J., Cairns E.J., Zhang Y.
Journal of the American Chemical Society, 2011
.
Factors Influencing the Quality of Carbon Coatings on LiFePO[sub 4]
Wilcox J.D., Doeff M.M., Marcinek M., Kostecki R.
Journal of the Electrochemical Society, 2007
.
Rechargeable lithium-sulfur batteries.
Manthiram A., Fu Y., Chung S., Zu C., Su Y.
Chemical Reviews, 2014
.
Designing high-energy lithium-sulfur batteries.
Seh Z.W., Sun Y., Zhang Q., Cui Y.
Chemical Society Reviews, 2016
.
Smaller sulfur molecules promise better lithium-sulfur batteries.
Xin S., Gu L., Zhao N., Yin Y., Zhou L., Guo Y., Wan L.
Journal of the American Chemical Society, 2012
.
Effect of carbon and N-doped carbon nanomaterials on the electrochemical performance of lithium titanate-based composites
Stenina I.A., Shaydullin R.R., Desyatov A.V., Kulova T.L., Yaroslavtsev A.B.
Electrochimica Acta, 2020
.
Trends in the Development of Room-Temperature Sodium–Sulfur Batteries
Novikova S.A., Voropaeva D.Y., Yaroslavtsev A.B.
Inorganic Materials, 2022
.
Ultramicroporous Carbon through an Activation-Free Approach for Li–S and Na–S Batteries in Carbonate-Based Electrolyte
.
Embedding Sulfur in MOF‐Derived Microporous Carbon Polyhedrons for Lithium–Sulfur Batteries
Wu H.B., Wei S., Zhang L., Xu R., Hng H.H., Lou X.W.
Chemistry - A European Journal, 2013
.
Perfluorosulfonic Acid Membrane for Lithium–Sulfur Batteries with S/C Cathodes
Yaroslavtsev A.B., Novikova S.A., Voropaeva D.Y., Li S.A., Kulova T.L.
Batteries, 2022
.
“Shuttle” in Polysulfide Shuttle: Friend or Foe?
Mistry A.N., Mukherjee P.P.
Journal of Physical Chemistry C, 2018
.
Insight into Sulfur Confined in Ultramicroporous Carbon
Helen M., Diemant T., Schindler S., Behm R.J., Danzer M., Kaiser U., Fichtner M., Anji Reddy M.
ACS Omega, 2018
.
A Collaboratively Polar Conductive Interface for Accelerating Polysulfide Redox Conversion
Cao B., Huang J., Mo Y., Xu C., Chen Y., Fang H.
ACS applied materials & interfaces, 2019
.
Possible Causes of Lithium–Sulfur Battery Degradation
Kulova T.L., Li S.A., Ryzhikova E.V., Skundin A.M.
Russian Journal of Electrochemistry, 2022
.
Mechanism of Cathodic Reduction of Sulfur
Kulova T.L., Li S.A., Ryzhikova E.V., Skundin A.M.
Russian Journal of Physical Chemistry A, 2021
.
Lithium-sulfur batteries: Problems and solutions
Kolosnitsyn V.S., Karaseva E.V.
Russian Journal of Electrochemistry, 2008
.
A microporous–mesoporous carbon with graphitic structure for a high-rate stable sulfur cathode in carbonate solvent-based Li–S batteries
Wang D., Zhou G., Li F., Wu K., Lu G.Q., Cheng H., Gentle I.R.
Physical Chemistry Chemical Physics, 2012
.
Carbon–sulfur composites for Li–S batteries: status and prospects
Wang D., Zeng Q., Zhou G., Yin L., Li F., Cheng H., Gentle I.R., Lu G.Q.
Journal of Materials Chemistry A, 2013
.
Catalytic oxidation of Li 2 S on the surface of metal sulfides for Li−S batteries
Zhou G., Tian H., Jin Y., Tao X., Liu B., Zhang R., Seh Z.W., Zhuo D., Liu Y., Sun J., Zhao J., Zu C., Wu D.S., Zhang Q., Cui Y., et. al.
Proceedings of the National Academy of Sciences of the United States of America, 2017
.
Single step transformation of sulphur to Li2S2/Li2S in Li-S batteries
Helen M., Reddy M.A., Diemant T., Golla-Schindler U., Behm R.J., Kaiser U., Fichtner M.
Scientific Reports, 2015
.
In situ synthesis of 3D sulfur-doped graphene/sulfur as a cathode material for lithium-sulfur batteries
Li N., Gan F., Wang P., Chen K., Chen S., He X.
Journal of Alloys and Compounds, 2018
.
A Li+-conductive microporous carbon–sulfur composite for Li-S batteries
Zhang W., Qiao D., Pan J., Cao Y., Yang H., Ai X.
Electrochimica Acta, 2013
.
Perspective on ultramicroporous carbon as sulphur host for Li–S batteries
Maria Joseph H., Fichtner M., Munnangi A.R.
Journal of Energy Chemistry, 2021
.
Engineering Strategies for Suppressing the Shuttle Effect in Lithium–Sulfur Batteries
Li J., Gao L., Pan F., Gong C., Sun L., Gao H., Zhang J., Zhao Y., Wang G., Liu H.
Nano-Micro Letters, 2023
.
Insights into the aspect ratio effects of ordered mesoporous carbon on the electrochemical performance of sulfur cathode in lithium-sulfur batteries
Xiang Y., Lu L., Zhang Y., Ersek G., Portale G., Li W., Zhang W., Kottapalli A.G., Pei Y.
Journal of Colloid and Interface Science, 2024