Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization

Upyrenko, Evgeny Vital'evich; Kurgachev, Dmitriy Andreevich

doi:10.1016/j.mencom.2024.04.044

Home / Publications / Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization

Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization

Evgeny Vital'evich Upyrenko ¹

Evgeny Vital'evich Upyrenko

,

Dmitriy Andreevich Kurgachev ¹

Dmitriy Andreevich Kurgachev

¹ Department of Chemistry, National Research Tomsk State University, Tomsk, Russian Federation

10.1016/j.mencom.2024.04.044

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Published 2024-04-22

Communication , Volume 34, Issue 3, 450-452

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Upyrenko E. V., Kurgachev D. A. Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 450-452.

GOST all authors (up to 50) Copy

Upyrenko E. V., Kurgachev D. A. Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 450-452.

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TY - JOUR

DO - 10.1016/j.mencom.2024.04.044

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.044

TI - Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization

T2 - Mendeleev Communications

AU - Upyrenko, Evgeny Vital'evich

AU - Kurgachev, Dmitriy Andreevich

PY - 2024

DA - 2024/04/22

PB - Mendeleev Communications

SP - 450-452

IS - 3

VL - 34

ER -

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@article{2024_Upyrenko,

author = {Evgeny Vital'evich Upyrenko and Dmitriy Andreevich Kurgachev},

title = {Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization},

journal = {Mendeleev Communications},

year = {2024},

volume = {34},

publisher = {Mendeleev Communications},

month = {Apr},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.044},

number = {3},

pages = {450--452},

doi = {10.1016/j.mencom.2024.04.044}

}

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Upyrenko, Evgeny Vital'evich, and Dmitriy Andreevich Kurgachev. “Hydrophilic interaction liquid chromatography: mixed-mode with advanced π-π selectivity realization.” Mendeleev Communications, vol. 34, no. 3, Apr. 2024, pp. 450-452. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.044.

Keywords

acetonitrile

hydrophilic interaction liquid chromatography

lipophilic matrix.

pentafluorophenyl stationary phase

tetrahydrofuran

π–π interactions

Abstract

Aprotic polar solvents do not suppress π-π interactions and polar stationary phase containing aromatic groups. The THF additives to MeCN/phosphate buffer mobile phase for hydrophilic interaction liquid chromatography operating in a mixed-mode eliminate lipophilic compounds interference saving unique π - π selectivity.

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