A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form

Dedov, Alexey Georgievich; Karavaev, Alexander Alexandrovich; Loktev, Alexey Sergeevich; Vagapova, Malika Nasrudinovna; Cherednichenko, Kirill Alekseevich; Maslakov, Konstantin Igorevich; Sadovnikov, Alexey Aleksandrovich; Molchanov, Sergey P

doi:10.1016/j.mencom.2024.04.039

Home / Publications / A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form

A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form

Alexey Georgievich Dedov ^{1, 2}

Alexey Georgievich Dedov

,

Alexander Alexandrovich Karavaev ^{1, 2}

Alexander Alexandrovich Karavaev

0000-0002-3258-9126

,

Alexey Sergeevich Loktev ^{1, 2}

Alexey Sergeevich Loktev

,

Malika Nasrudinovna Vagapova ¹

Malika Nasrudinovna Vagapova

,

Kirill Alekseevich Cherednichenko ²

Kirill Alekseevich Cherednichenko

,

Konstantin Igorevich Maslakov ³

Konstantin Igorevich Maslakov

0000-0002-0672-2683

,

Alexey Aleksandrovich Sadovnikov ¹

Alexey Aleksandrovich Sadovnikov

,

Sergey P Molchanov ¹

Sergey P Molchanov

¹ A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

² National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation

³ Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

10.1016/j.mencom.2024.04.039

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Published 2024-04-22

Communication , Volume 34, Issue 3, 433-435

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Dedov A. G. et al. A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 433-435.

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Dedov A. G., Karavaev A. A., Loktev A. S., Vagapova M. N., Cherednichenko K. A., Maslakov K. I., Sadovnikov A. A., Molchanov S. P. A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 433-435.

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TY - JOUR

DO - 10.1016/j.mencom.2024.04.039

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.039

TI - A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form

T2 - Mendeleev Communications

AU - Dedov, Alexey Georgievich

AU - Karavaev, Alexander Alexandrovich

AU - Loktev, Alexey Sergeevich

AU - Vagapova, Malika Nasrudinovna

AU - Cherednichenko, Kirill Alekseevich

AU - Maslakov, Konstantin Igorevich

AU - Sadovnikov, Alexey Aleksandrovich

AU - Molchanov, Sergey P

PY - 2024

DA - 2024/04/22

PB - Mendeleev Communications

SP - 433-435

IS - 3

VL - 34

ER -

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@article{2024_Dedov,

author = {Alexey Georgievich Dedov and Alexander Alexandrovich Karavaev and Alexey Sergeevich Loktev and Malika Nasrudinovna Vagapova and Kirill Alekseevich Cherednichenko and Konstantin Igorevich Maslakov and Alexey Aleksandrovich Sadovnikov and Sergey P Molchanov},

title = {A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form},

journal = {Mendeleev Communications},

year = {2024},

volume = {34},

publisher = {Mendeleev Communications},

month = {Apr},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.039},

number = {3},

pages = {433--435},

doi = {10.1016/j.mencom.2024.04.039}

}

MLA

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Dedov, Alexey Georgievich, et al. “A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form.” Mendeleev Communications, vol. 34, no. 3, Apr. 2024, pp. 433-435. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.039.

Keywords

hydrothermal-microwave synthesis

interparticle porosity.

MFI

micro/mesopores

nanosized ZSM-5 zeolite

proton form

Abstract

A new method for the synthesis of nanosized ZSM-5 zeolite with the MFI structure in the proton form is reported. The material was synthesized by the hydrothermal-microwave method and characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, atomic force microscopy, low-temperature nitrogen physisorption, thermal desorption of ammonia and solid- state 27Al NMR. The synthesized material is formed by zeolite particles of 30-80 nm in size, which ensures its high specific surface area, pore volume and interparticle porosity.

References

.

10.1016/j.micromeso.2021.111262

Microwave synthesis of zeolites and their related applications

Zeng X., Hu X., Song H., Xia G., Shen Z., Yu R., Moskovits M.

Microporous and Mesoporous Materials, 2021

.

10.1016/j.cattod.2020.04.064

Isobutanol conversion to petrochemicals using MFI-based catalysts synthesized by a hydrothermal-microwave method

Dedov A.G., Karavaev A.A., Loktev A.S., Mitinenko A.S., Moiseev I.I.

Catalysis Today, 2021

.

10.1080/10406638.2020.1833048

Modified ZSM-5 Zeolite for Conversion of LPG to Aromatics

Hajimirzaee S., Soleimani Mehr A., Kianfar E.

Polycyclic Aromatic Compounds, 2020

.

10.1038/s44160-022-00091-8

Synthesis strategies and design principles for nanosized and hierarchical zeolites

Mallette A.J., Seo S., Rimer J.D.

Nature Synthesis, 2022

.

10.1016/j.jechem.2016.09.011

Fabrication of a nano-sized ZSM-5 zeolite with intercrystalline mesopores for conversion of methanol to gasoline

Fu T., Chang J., Shao J., Li Z.

Journal of Energy Chemistry, 2017

.

10.1016/j.cattod.2014.01.037

Conversion of ethanol to hydrocarbons on hierarchical HZSM-5 zeolites

Ramasamy K.K., Zhang H., Sun J., Wang Y.

Catalysis Today, 2014

.

10.1016/j.apcata.2014.12.019

Acid catalytic function of mesopore walls generated by MFI zeolite desilication in comparison with external surfaces of MFI zeolite nanosheet

Jung J., Jo C., Mota F.M., Cho J., Ryoo R.

Applied Catalysis A: General, 2015

.

10.1016/s1872-2067(15)61038-5

Nanosized and hierarchical zeolites: A short review

Koohsaryan E., Anbia M.

Chinese Journal of Catalysis, 2016

.

10.1016/j.matdes.2016.03.035

Nanosized Sn-MFI zeolite for selective detection of exhaust gases

Talapaneni S.N., Grand J., Thomas S., Ahmad H.A., Mintova S.

Materials and Design, 2016

.

10.1016/j.apcata.2017.01.005

Synthesis of isomorphous MFI nanosheet zeolites for supercritical catalytic cracking of n-dodecane

Ji Y., Shi B., Yang H., Yan W.

Applied Catalysis A: General, 2017

.

10.1016/j.catcom.2017.06.048

Aggregates of nano-sized ZSM-5 crystals synthesized with template-free and alkali-treated seeds for improving the catalytic performance in MTP reaction

Chen H., Wang Y., Sun C., Gao F., Sun L., Wang C., Wang Z., Wang X.

Catalysis Communications, 2017

.

10.1016/j.apcata.2017.09.035

Relating coke formation and characteristics to deactivation of ZSM-5 zeolite in methanol to gasoline conversion

Wan Z., Li G.K., Wang C., Yang H., Zhang D.

Applied Catalysis A: General, 2018

.

10.1016/j.apcata.2018.08.018

Synthesis and catalytic testing of Lewis acidic nano-MFI zeolites for the epoxide ring opening reaction with alcohol

Parulkar A., Joshi R., Deshpande N., Brunelli N.A.

Applied Catalysis A: General, 2018

.

10.1016/j.micromeso.2013.03.016

Effectiveness of nano-scale ZSM-5 zeolite and its deactivation mechanism on catalytic cracking of representative hydrocarbons of naphtha

Konno H., Tago T., Nakasaka Y., Ohnaka R., Nishimura J., Masuda T.

Microporous and Mesoporous Materials, 2013

.

10.1016/j.micromeso.2018.07.007

Controllable synthesis of nano-ZSM-5 catalysts with large amount and high strength of acid sites for conversion of methanol to hydrocarbons

Shao J., Fu T., Ma Q., Ma Z., Zhang C., Li Z.

Microporous and Mesoporous Materials, 2019

.

10.1016/j.micromeso.2012.02.014

Facile synthesis of nano-sized NH4-ZSM-5 zeolites

Xue T., Wang Y.M., He M.

Microporous and Mesoporous Materials, 2012

.

10.1016/j.jcat.2019.05.030

Unveiling coke formation mechanism in MFI zeolites during methanol-to-hydrocarbons conversion

Lee S., Choi M.

Journal of Catalysis, 2019

.

10.1016/j.jcis.2011.06.020

Facile synthesis of hierarchical nanocrystalline ZSM-5 zeolite under mild conditions and its catalytic performance

Ni Y., Sun A., Wu X., Hai G., Hu J., Li T., Li G.

Journal of Colloid and Interface Science, 2011

.

10.1016/j.micromeso.2008.11.005

Microwave-assisted hydrothermal synthesis of nanozeolites with controllable size

Hu Y., Liu C., Zhang Y., Ren N., Tang Y.

Microporous and Mesoporous Materials, 2009

.

10.1016/j.catcom.2009.04.021

The effect of micro and nano particle sizes of H-ZSM-5 on the selectivity of MTP reaction

Firoozi M., Baghalha M., Asadi M.

Catalysis Communications, 2009

.

10.1016/s1872-2067(20)63775-5

Methane combustion over palladium catalyst within the confined space of MFI zeolite

Gao M., Gong Z., Weng X., Shang W., Chai Y., Dai W., Wu G., Guan N., Li L.

Chinese Journal of Catalysis, 2021

.

10.1016/j.scitotenv.2022.157658

Catalytic reforming of polyethylene pyrolysis vapors to naphtha range hydrocarbons with low aromatic content over a high silica ZSM-5 zeolite

Dai L., Zhou N., Lv Y., Cobb K., Chen P., Wang Y., Liu Y., Zou R., Lei H., Mohamed B.A., Ruan R., Cheng Y.

Science of the Total Environment, 2022

.

10.1016/j.micromeso.2022.111926

A theoretical insight into diffusion mechanism of benzene-methanol alkylation reaction in ZSM-5 zeolite

Yan Z., Chen D., Huang L., Liu J., Fu H., Xiao Y., Li S.

Microporous and Mesoporous Materials, 2022

.

10.1016/j.apcatb.2022.121582

Stable and reusable hierarchical ZSM-5 zeolite with superior performance for olefin oligomerization when partially coked

Mohamed H.O., Parsapur R.K., Hita I., Cerrillo J.L., Ramírez A., Huang K., Gascon J., Castaño P.

Applied Catalysis B: Environmental, 2022

.

10.1016/j.cattod.2022.06.026

Fundamental understanding and catalytic applications of hollow MFI-type zeolites

Wang R., Xia C., Peng B.

Catalysis Today, 2022

.

10.1016/j.mencom.2023.10.031

HMFI/SiC – A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion

Dedov A.G., Karavaev A.A., Loktev A.S., Zemlianskii P.V., Vagapova M.N., Maslakov K.I., Cherednichenko K.A., Egazar'yants S.V., Khoroshilov A.V., Ivanov P.I.

Mendeleev Communications, 2023