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Displacement of methoxy groups by thiol residues on the fullerene cage

Olga Alexandrovna Kraevaya 1
Olga Alexandrovna Kraevaya
, 
Alexander Vladimirovich Chernyak 1, 2
Alexander Vladimirovich Chernyak
, 
Alexander Fedorovich Shestakov 1, 3
Alexander Fedorovich Shestakov
, 
Pavel Anatol'evich Troshin 1, 4
Pavel Anatol'evich Troshin
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2 Yu.A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
3 Department of Fundamental Physical and Chemical Engineering, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
4 Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou, China
10.1016/j.mencom.2024.04.032
Published 2024-04-22
Communication , Volume 34, Issue 3, 411-413
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Kraevaya O. A. et al. Displacement of methoxy groups by thiol residues on the fullerene cage // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 411-413.
GOST all authors (up to 50) Copy
Kraevaya O. A., Chernyak A. V., Shestakov A. F., Troshin P. A. Displacement of methoxy groups by thiol residues on the fullerene cage // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 411-413.
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TY - JOUR
DO - 10.1016/j.mencom.2024.04.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.032
TI - Displacement of methoxy groups by thiol residues on the fullerene cage
T2 - Mendeleev Communications
AU - Kraevaya, Olga Alexandrovna
AU - Chernyak, Alexander Vladimirovich
AU - Shestakov, Alexander Fedorovich
AU - Troshin, Pavel Anatol'evich
PY - 2024
DA - 2024/04/22
PB - Mendeleev Communications
SP - 411-413
IS - 3
VL - 34
ER -
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@article{2024_Kraevaya,
author = {Olga Alexandrovna Kraevaya and Alexander Vladimirovich Chernyak and Alexander Fedorovich Shestakov and Pavel Anatol'evich Troshin},
title = {Displacement of methoxy groups by thiol residues on the fullerene cage},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.032},
number = {3},
pages = {411--413},
doi = {10.1016/j.mencom.2024.04.032}
}
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MLA Copy
Kraevaya, Olga Alexandrovna, et al. “Displacement of methoxy groups by thiol residues on the fullerene cage.” Mendeleev Communications, vol. 34, no. 3, Apr. 2024, pp. 411-413. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.032.

Keywords

alcohols
alkoxy fullerene derivative
cyclopentadienyl-type addition pattern
substitution
sulfides
thiols

Abstract

Methoxy groups on the fullerene cage in compound C60(OMe)5Br were displaced by thiol residues of methyl 3-mercaptopropanoate thus leading to C60(SCH2CH2CO2Me)5H product. The structure of the product was established by NMR spectroscopy.

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