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Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure

Adel Il'darovich Gaysin 1
Adel Il'darovich Gaysin
, 
Tatyana Anatol'evna Vakhonina 1
Tatyana Anatol'evna Vakhonina
, 
Ekaterina Olegovna Yakovleva 1
Ekaterina Olegovna Yakovleva
, 
Marina Yur'evna Balakina 1
Marina Yur'evna Balakina
, 
1 A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
10.1016/j.mencom.2024.04.007
Published 2024-04-22
Communication , Volume 34, Issue 3, 332-334
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Gaysin A. I. et al. Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 332-334.
GOST all authors (up to 50) Copy
Gaysin A. I., Vakhonina T. A., Yakovleva E. O., Balakina M. Y., Sinyashin O. G. Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 332-334.
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TY - JOUR
DO - 10.1016/j.mencom.2024.04.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.007
TI - Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure
T2 - Mendeleev Communications
AU - Gaysin, Adel Il'darovich
AU - Vakhonina, Tatyana Anatol'evna
AU - Yakovleva, Ekaterina Olegovna
AU - Balakina, Marina Yur'evna
AU - Sinyashin, Oleg Gerol'dovich
PY - 2024
DA - 2024/04/22
PB - Mendeleev Communications
SP - 332-334
IS - 3
VL - 34
ER -
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@article{2024_Gaysin,
author = {Adel Il'darovich Gaysin and Tatyana Anatol'evna Vakhonina and Ekaterina Olegovna Yakovleva and Marina Yur'evna Balakina and Oleg Gerol'dovich Sinyashin},
title = {Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.007},
number = {3},
pages = {332--334},
doi = {10.1016/j.mencom.2024.04.007}
}
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MLA Copy
Gaysin, Adel Il'darovich, et al. “Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure.” Mendeleev Communications, vol. 34, no. 3, Apr. 2024, pp. 332-334. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.04.007.

Keywords

2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate.
comonomer reactivity ratios
copolymer microstructure
methacrylic copolymers
nonlinear optical polymers
probability of bonds formation
radical polymerization

Abstract

A precursor for the production of azo chromophores, viz. 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate, was prepared and characterized. Its copolymerization with methyl methacrylate was carried out and the copolymerization constants were determined: for 2-hydroxy-3-(N-methyl-N-phenylamino) propyl methacrylate, r1 = 0.50; for methyl methacrylate, r2 = 0.93. The average block lengths of monomers of the same type depending on the composition of the copolymer were estimated.

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