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Why naturally occurring quinone redox systems lack amino groups: consideration using 1,4-naphthoquinone derivatives

Alexander Fedorovich Pozharskii 1
Alexander Fedorovich Pozharskii
, 
Marina Pavlovna Vlasenko 1
Marina Pavlovna Vlasenko
, 
Pavel Anatol'evich Knyazev 2
Pavel Anatol'evich Knyazev
, 
Andrey Georgievich Starikov 2
Andrey Georgievich Starikov
1 Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
2 Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
10.1016/j.mencom.2024.02.028
Published 2024-02-19
Communication , Volume 34, Issue 2, 246-250
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Pozharskii A. F. et al. Why naturally occurring quinone redox systems lack amino groups: consideration using 1,4-naphthoquinone derivatives // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 246-250.
GOST all authors (up to 50) Copy
Pozharskii A. F., Vlasenko M. P., Knyazev P. A., Starikov A. G. Why naturally occurring quinone redox systems lack amino groups: consideration using 1,4-naphthoquinone derivatives // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 246-250.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.028
TI - Why naturally occurring quinone redox systems lack amino groups: consideration using 1,4-naphthoquinone derivatives
T2 - Mendeleev Communications
AU - Pozharskii, Alexander Fedorovich
AU - Vlasenko, Marina Pavlovna
AU - Knyazev, Pavel Anatol'evich
AU - Starikov, Andrey Georgievich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 246-250
IS - 2
VL - 34
ER -
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@article{2024_Pozharskii,
author = {Alexander Fedorovich Pozharskii and Marina Pavlovna Vlasenko and Pavel Anatol'evich Knyazev and Andrey Georgievich Starikov},
title = {Why naturally occurring quinone redox systems lack amino groups: consideration using 1,4-naphthoquinone derivatives},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.028},
number = {2},
pages = {246--250},
doi = {10.1016/j.mencom.2024.02.028}
}
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Pozharskii, Alexander Fedorovich, et al. “Why naturally occurring quinone redox systems lack amino groups: consideration using 1,4-naphthoquinone derivatives.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 246-250. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.028.

Keywords

1
4-naphthoquinones
amines
oxidation
radical anions.
reduction

Abstract

Four representatives of amino derivatives of 1,4-naphtho-quinone were examined by combination of cyclic voltammetry, ESR spectroscopy and quantum chemical calculations. The results obtained help to rationalize why natural quinonoid redox systems do not contain amino groups so common in proteins, nucleobases, numerous signal and other biologically important molecules.

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