Home / Publications / Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)

Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)

Aleksandr Shailovich Samarin 1
Aleksandr Shailovich Samarin
, 
Tatiana Vital'evna Ivanova 1, 2
Tatiana Vital'evna Ivanova
, 
Eugene Evgen'evich Nazarov 1
Eugene Evgen'evich Nazarov
,  , 
Nikita Dmitrievich Luchinin 1
Nikita Dmitrievich Luchinin
, 
Evgenii Viktorovich Antipov 1, 3
Evgenii Viktorovich Antipov
, 
2 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
3 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.02.027
Published 2024-02-19
Communication , Volume 34, Issue 2, 242-245
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Samarin A. S. et al. Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe) // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 242-245.
GOST all authors (up to 50) Copy
Samarin A. S., Ivanova T. V., Nazarov E. E., Marshenya S. N., Luchinin N. D., Antipov E. V., Fedotov S. S. Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe) // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 242-245.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.027
TI - Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)
T2 - Mendeleev Communications
AU - Samarin, Aleksandr Shailovich
AU - Ivanova, Tatiana Vital'evna
AU - Nazarov, Eugene Evgen'evich
AU - Marshenya, Sergey Nikolaevich
AU - Luchinin, Nikita Dmitrievich
AU - Antipov, Evgenii Viktorovich
AU - Fedotov, Stanislav Sergeyevich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 242-245
IS - 2
VL - 34
ER -
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@article{2024_Samarin,
author = {Aleksandr Shailovich Samarin and Tatiana Vital'evna Ivanova and Eugene Evgen'evich Nazarov and Sergey Nikolaevich Marshenya and Nikita Dmitrievich Luchinin and Evgenii Viktorovich Antipov and Stanislav Sergeyevich Fedotov},
title = {Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.027},
number = {2},
pages = {242--245},
doi = {10.1016/j.mencom.2024.02.027}
}
MLA
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Samarin, Aleksandr Shailovich, et al. “Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe).” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 242-245. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.027.

Keywords

battery
cathode material
chimie douce
dittmarite
maricite
natrophilite
olivine
topochemical reaction
triphylite

Abstract

Phase-pure NaMPO4 (M = Mn, Mn/Fe; isotypic to triphylite) and Li(Mn/Fe)PO4 were isolated as a result of the low- temperature reaction between NH4MPO4·H2O (M = Mn, Mn/Fe) and AcONa·3H2O or AcOLi, respectively. Electrochemical tests in half-cells revealed that Na-based compounds exhibit poor electrochemical activity vs. metallic Na, while the similarly synthesized Li counterpart demonstrates decent cycling in Na cells. The synthetic features, crystal structures and properties of related members of the olivine family are discussed.

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