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Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes

Svetlana A Kuznetsova 1
Svetlana A Kuznetsova
, 
Safar Mukhtarovich Yunusov 1
Safar Mukhtarovich Yunusov
, 
Ekaterina Aleksandrovna Khakina 1
Ekaterina Aleksandrovna Khakina
,  ,  , 
Elena Stepanovna Kalyuzhnaya 1
Elena Stepanovna Kalyuzhnaya
, 
Mikhail Mikhailovich, Jr Ilyin 1
Mikhail Mikhailovich, Jr Ilyin
, 
Viacheslav Vadimovich Morozov 1, 2
Viacheslav Vadimovich Morozov
, 
Alexey Sergeyevich Kashin 3
Alexey Sergeyevich Kashin
, 
Yurii Nikolaevich Belokon 1
Yurii Nikolaevich Belokon
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
10.1016/j.mencom.2024.02.014
Published 2024-02-19
Communication , Volume 34, Issue 2, 204-205
2
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Kuznetsova S. A. et al. Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 204-205.
GOST all authors (up to 50) Copy
Kuznetsova S. A., Yunusov S. M., Khakina E. A., Naumkin A. V., Chusov D. A., Kalyuzhnaya E. S., Ilyin M. M. J., Morozov V. V., Kashin A. S., Belokon Y. N. Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 204-205.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.014
TI - Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes
T2 - Mendeleev Communications
AU - Kuznetsova, Svetlana A
AU - Yunusov, Safar Mukhtarovich
AU - Khakina, Ekaterina Aleksandrovna
AU - Naumkin, Alexander Vasil'evich
AU - Chusov, Denis Alexandrovich
AU - Kalyuzhnaya, Elena Stepanovna
AU - Ilyin, Mikhail Mikhailovich, Jr
AU - Morozov, Viacheslav Vadimovich
AU - Kashin, Alexey Sergeyevich
AU - Belokon, Yurii Nikolaevich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 204-205
IS - 2
VL - 34
ER -
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@article{2024_Kuznetsova,
author = {Svetlana A Kuznetsova and Safar Mukhtarovich Yunusov and Ekaterina Aleksandrovna Khakina and Alexander Vasil'evich Naumkin and Denis Alexandrovich Chusov and Elena Stepanovna Kalyuzhnaya and Mikhail Mikhailovich, Jr Ilyin and Viacheslav Vadimovich Morozov and Alexey Sergeyevich Kashin and Yurii Nikolaevich Belokon},
title = {Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.014},
number = {2},
pages = {204--205},
doi = {10.1016/j.mencom.2024.02.014}
}
MLA
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Kuznetsova, Svetlana A., et al. “Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 204-205. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.014.

Keywords

crystal organic salts
heterogeneous hydrogenation
ionic frameworks.
nitroarenes
palladium nanoparticles
selective reduction
stabilization of nanoparticles

Abstract

A novel catalyst based on Pd nanoparticles encapsulated in a chiral crystalline organic salt matrix is prepared from tetrasodium tetrakis(4-sulfonatophenyl)methane and tetrakis[4-(S)-prolinamidophenyl]methane in water at room temperature under hydrogen atmosphere. The hydrogenation of p-nitrobenzaldehyde over this catalyst stalls at the stage of p-aminobenzyl alcohol, whereas Pd/C brings the reduction further to p-toluidine.

References

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