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Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from L-proline

Roman Olegovich Burlutsky 1
Roman Olegovich Burlutsky
, 
Ella Sergeevna Yudina 1
Ella Sergeevna Yudina
, 
Andrei Viktorovich Churakov 2
Andrei Viktorovich Churakov
, 
Dmitrii Anatol'evich Lemenovskii 1
Dmitrii Anatol'evich Lemenovskii
, 
Viktor Prokhorovich Dyadchenko 1
Viktor Prokhorovich Dyadchenko
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.02.013
Published 2024-02-19
Communication , Volume 34, Issue 2, 201-203
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Burlutsky R. O. et al. Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from L-proline // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 201-203.
GOST all authors (up to 50) Copy
Burlutsky R. O., Yudina E. S., Churakov A. V., Lemenovskii D. A., Dyadchenko V. P. Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from L-proline // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 201-203.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.013
TI - Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from L-proline
T2 - Mendeleev Communications
AU - Burlutsky, Roman Olegovich
AU - Yudina, Ella Sergeevna
AU - Churakov, Andrei Viktorovich
AU - Lemenovskii, Dmitrii Anatol'evich
AU - Dyadchenko, Viktor Prokhorovich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 201-203
IS - 2
VL - 34
ER -
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@article{2024_Burlutsky,
author = {Roman Olegovich Burlutsky and Ella Sergeevna Yudina and Andrei Viktorovich Churakov and Dmitrii Anatol'evich Lemenovskii and Viktor Prokhorovich Dyadchenko},
title = {Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from L-proline},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.013},
number = {2},
pages = {201--203},
doi = {10.1016/j.mencom.2024.02.013}
}
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Burlutsky, Roman Olegovich, et al. “Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from L-proline.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 201-203. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.013.

Keywords

asymmetric organocatalysis
benzyloxycarbonyl protective group
chiral secondary alcohols
diethylzinc.
enantioselective addition
ferrocene
ferrocenylmagnesium bromide
proline
X-ray molecular structure

Abstract

New ferrocenyl-containing diastereomeric secondary alcohols derived from L-proline of (ferrocenyl)(pyrrolidin-2-yl)methanol chemotype were synthesized. Their crystal and molecular structure was explored. The prepared chiral secondary and tertiary alcohols in which hydroxy group is sterically hindered by ferrocene substituents show asymmetric induction effect in reaction between diethylzinc and benzaldehyde.

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Burlutsky R.O., Yudina E.S., Churakov A.V., Lemenovskiy D.A., Dyadchenko V.P.
Mendeleev Communications, 2024