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pH-Dependent molecular switch based on Pv porphyrin

Evgeniya Aleksandrovna Safonova 1
Evgeniya Aleksandrovna Safonova
Marina Aleksandrovna Polovkova
Alexander Germanovich Martynov 1
Alexander Germanovich Martynov
Gayane Artavazdovna Kirakosyan 1, 2
Gayane Artavazdovna Kirakosyan
Aslan Yusupovich Tsivadze 1, 2
Aslan Yusupovich Tsivadze
Yulia Germanovna Gorbunova
1 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
Published 2024-02-19
CommunicationVolume 34, Issue 2, 167-169
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Efimova I. A. et al. pH-Dependent molecular switch based on Pv porphyrin // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 167-169.
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Efimova I. A., Safonova E. A., Polovkova M. A., Martynov A. G., Kirakosyan G. A., Tsivadze A. Y., Gorbunova Y. G. pH-Dependent molecular switch based on Pv porphyrin // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 167-169.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.003
TI - pH-Dependent molecular switch based on Pv porphyrin
T2 - Mendeleev Communications
AU - Efimova, Inessa Andreevna
AU - Safonova, Evgeniya Aleksandrovna
AU - Polovkova, Marina Aleksandrovna
AU - Martynov, Alexander Germanovich
AU - Kirakosyan, Gayane Artavazdovna
AU - Tsivadze, Aslan Yusupovich
AU - Gorbunova, Yulia Germanovna
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 167-169
IS - 2
VL - 34
ER -
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@article{2024_Efimova,
author = {Inessa Andreevna Efimova and Evgeniya Aleksandrovna Safonova and Marina Aleksandrovna Polovkova and Alexander Germanovich Martynov and Gayane Artavazdovna Kirakosyan and Aslan Yusupovich Tsivadze and Yulia Germanovna Gorbunova},
title = {pH-Dependent molecular switch based on Pv porphyrin},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.003},
number = {2},
pages = {167--169},
doi = {10.1016/j.mencom.2024.02.003}
}
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Cite this
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Efimova, Inessa Andreevna, et al. “pH-Dependent molecular switch based on Pv porphyrin.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 167-169. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.003.

Keywords

fluorescence
molecular switches
phosphorus
porphyrin
protonation.
singlet oxygen

Abstract

Water-soluble phosphorus(v) porphyrin with p-amino- phenoxy groups as axial ligands was obtained, and its photophysical and photochemical properties were investigated and rationalized using quantum chemical calculations. It was demonstrated that at pH ≥ 6.1 this porphyrin did not emit or generate singlet oxygen, whereas at pH ≤ 2.0 it completely converted into the N-protonated form, which exhibited fluorescence and the ability to generate singlet oxygen.

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