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Coordination and hydrogen bonding diversity of OOH ligand in crystalline organoelement and inorganic hydroperoxides

Ivan Andreevich Buldashov 1, 2
Ivan Andreevich Buldashov
, 
Alexander G Medvedev 1
Alexander G Medvedev
, 
Alexey Aleksandrovich Mikhaylov 1
Alexey Aleksandrovich Mikhaylov
, 
Andrei Viktorovich Churakov 1
Andrei Viktorovich Churakov
, 
Petr Valer'evich Prikhodchenko 1
Petr Valer'evich Prikhodchenko
2 National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
10.1016/j.mencom.2024.02.002
Published 2024-02-19
Communication , Volume 34, Issue 2, 156-166
5
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Buldashov I. A. et al. Coordination and hydrogen bonding diversity of OOH ligand in crystalline organoelement and inorganic hydroperoxides // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 156-166.
GOST all authors (up to 50) Copy
Buldashov I. A., Medvedev A. G., Mikhaylov A. A., Churakov A. V., Prikhodchenko P. V. Coordination and hydrogen bonding diversity of OOH ligand in crystalline organoelement and inorganic hydroperoxides // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 156-166.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.002
TI - Coordination and hydrogen bonding diversity of OOH ligand in crystalline organoelement and inorganic hydroperoxides
T2 - Mendeleev Communications
AU - Buldashov, Ivan Andreevich
AU - Medvedev, Alexander G
AU - Mikhaylov, Alexey Aleksandrovich
AU - Churakov, Andrei Viktorovich
AU - Prikhodchenko, Petr Valer'evich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 156-166
IS - 2
VL - 34
ER -
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@article{2024_Buldashov,
author = {Ivan Andreevich Buldashov and Alexander G Medvedev and Alexey Aleksandrovich Mikhaylov and Andrei Viktorovich Churakov and Petr Valer'evich Prikhodchenko},
title = {Coordination and hydrogen bonding diversity of OOH ligand in crystalline organoelement and inorganic hydroperoxides},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.002},
number = {2},
pages = {156--166},
doi = {10.1016/j.mencom.2024.02.002}
}
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Cite this
MLA Copy
Buldashov, Ivan Andreevich, et al. “Coordination and hydrogen bonding diversity of OOH ligand in crystalline organoelement and inorganic hydroperoxides.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 156-166. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.002.

Keywords

coordination mode
crystal packing
hydrogen bonding.
hydroperoxo ligand
inorganic hydroperoxide
organoelement hydroperoxide

Abstract

Hydroperoxo complexes, that is coordination compounds with directly bound hydroperoxo ligands OOH−, are encountered and applied in various fields such as catalytic oxygenations and functional material precursors. This focus article spotlights a hydroperoxo ligand as a key moiety providing the reactivity of these complexes and stabilization of their crystal structures through hydrogen bonding. The diversity of hydroperoxo coordination types and hydrogen-bonded motifs is demonstrated for the crystalline organoelement and inorganic hydroperoxides presented in the structural databases.

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