Home / Publications / Electrochemical transformations of CH-acids

Electrochemical transformations of CH-acids

, 
Anatoly Nikolaevich Vereshchagin 1
Anatoly Nikolaevich Vereshchagin
, 
Yuliya Evgenievna Ryzhkova 1
Yuliya Evgenievna Ryzhkova
, 
Fedor Vladimirovich Ryzhkov 1
Fedor Vladimirovich Ryzhkov
10.1016/j.mencom.2024.02.001
Published 2024-02-19
Communication , Volume 34, Issue 2, 145-155
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Elinson M. N. et al. Electrochemical transformations of CH-acids // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 145-155.
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Elinson M. N., Vereshchagin A. N., Ryzhkova Y. E., Ryzhkov F. V. Electrochemical transformations of CH-acids // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 145-155.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.001
TI - Electrochemical transformations of CH-acids
T2 - Mendeleev Communications
AU - Elinson, Michail Nikolaevich
AU - Vereshchagin, Anatoly Nikolaevich
AU - Ryzhkova, Yuliya Evgenievna
AU - Ryzhkov, Fedor Vladimirovich
PY - 2024
DA - 2024/02/19
PB - Mendeleev Communications
SP - 145-155
IS - 2
VL - 34
ER -
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@article{2024_Elinson,
author = {Michail Nikolaevich Elinson and Anatoly Nikolaevich Vereshchagin and Yuliya Evgenievna Ryzhkova and Fedor Vladimirovich Ryzhkov},
title = {Electrochemical transformations of CH-acids},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.001},
number = {2},
pages = {145--155},
doi = {10.1016/j.mencom.2024.02.001}
}
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Elinson, Michail Nikolaevich, et al. “Electrochemical transformations of CH-acids.” Mendeleev Communications, vol. 34, no. 2, Feb. 2024, pp. 145-155. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.02.001.

Keywords

anodic processes
cascade reactions
cathodic processes
chain reactions
Cyclopropanes
electrochemical synthesis
mediators
multi- component reactions
spirocyclic compounds.

Abstract

Electroorganic synthesis is an environmentally friendly methodology for the oxidation and the reduction of organic compounds, since dangerous and toxic redox reagents are replaced by electric current, and the overall energy consumption is reduced. Although the electrochemical step is usually just one part of a multi-step sequence, it constitutes a key process for the generation of a variety of reactive intermediates. Therefore, organic electrochemistry often provides interesting and valuable alternatives to conventional synthetic methods and serves as a useful tool for an organic chemist. The unique electrocatalytic cascade and multicomponent transformations of CH-acids are discussed in this review. The review also reflects modern trends in the use of electrochemically induced chain reactions in cascade and multicomponent electroorganic synthesis.

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