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An efficient synthesis of substituted 4,5-dihydroxyimidazolidin-2-ones by oxidation of imidazolin-2-ones with HNO3

Vladimir Vladimirovich Baranov 1
Vladimir Vladimirovich Baranov
, 
Pavel D Prakhov 1, 2
Pavel D Prakhov
, 
Natal'ya Georgievna Kolotyrkina 1
Natal'ya Georgievna Kolotyrkina
, 
Angelina Nikolaevna Kravchenko 1
Angelina Nikolaevna Kravchenko
2 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
10.1016/j.mencom.2024.01.035
Published 2023-12-25
Communication , Volume 34, Issue 1, 116-118
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Baranov V. V. et al. An efficient synthesis of substituted 4,5-dihydroxyimidazolidin-2-ones by oxidation of imidazolin-2-ones with HNO3 // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 116-118.
GOST all authors (up to 50) Copy
Baranov V. V., Prakhov P. D., Kolotyrkina N. G., Kravchenko A. N. An efficient synthesis of substituted 4,5-dihydroxyimidazolidin-2-ones by oxidation of imidazolin-2-ones with HNO3 // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 116-118.
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TY - JOUR
DO - 10.1016/j.mencom.2024.01.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.035
TI - An efficient synthesis of substituted 4,5-dihydroxyimidazolidin-2-ones by oxidation of imidazolin-2-ones with HNO3
T2 - Mendeleev Communications
AU - Baranov, Vladimir Vladimirovich
AU - Prakhov, Pavel D
AU - Kolotyrkina, Natal'ya Georgievna
AU - Kravchenko, Angelina Nikolaevna
PY - 2023
DA - 2023/12/25
PB - Mendeleev Communications
SP - 116-118
IS - 1
VL - 34
ER -
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@article{2023_Baranov,
author = {Vladimir Vladimirovich Baranov and Pavel D Prakhov and Natal'ya Georgievna Kolotyrkina and Angelina Nikolaevna Kravchenko},
title = {An efficient synthesis of substituted 4,5-dihydroxyimidazolidin-2-ones by oxidation of imidazolin-2-ones with HNO3},
journal = {Mendeleev Communications},
year = {2023},
volume = {34},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.035},
number = {1},
pages = {116--118},
doi = {10.1016/j.mencom.2024.01.035}
}
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Baranov, Vladimir Vladimirovich, et al. “An efficient synthesis of substituted 4,5-dihydroxyimidazolidin-2-ones by oxidation of imidazolin-2-ones with HNO3.” Mendeleev Communications, vol. 34, no. 1, Dec. 2023, pp. 116-118. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.035.
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Keywords

4
4-imidazolin-2-ones
5-dihydroxyimidazolidin-2-ones
acyloins
diastereomers
nitric acid
oxidation
ureas.

Abstract

Previously unavailable 1,3-dialkyl-4,5-diaryl-4,5-dihydroxyimidazolidin-2-ones were obtained by the oxidation of 1,3-dialkyl-4,5-diaryl-4-imidazolin-2-ones with HNO3 (65 or 84% aq.). The scope of required 4-imidazolin-2-ones obtained from acyloins has been expanded, which provided preparation of new representatives of the title compounds.

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