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Quaternary phosphonium salts based on quinopimaric acid

Anastasiya M Shinkareva 1
Anastasiya M Shinkareva
Andrey Vladimirovich Nemtarev
Denis Vladimirovich Chachkov 3
Denis Vladimirovich Chachkov
Alexey Borisovich Dobrynin 2
Alexey Borisovich Dobrynin
Igor Anatol'evich Litvinov 2
Igor Anatol'evich Litvinov
1 Kazan Federal University, Kazan, Russian Federation
2 A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
3 Kazan Department of Joint Supercomputer Center, Scientific Research Institute for System Analysis, Russian Academy of Sciences, Kazan, Russian Federation
Published 2023-12-25
CommunicationVolume 34, Issue 1, 113-115
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Shinkareva A. M. et al. Quaternary phosphonium salts based on quinopimaric acid // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 113-115.
GOST all authors (up to 50) Copy
Shinkareva A. M., Nemtarev A. V., Chachkov D. V., Dobrynin A. B., Litvinov I. A., Mironov V. F. Quaternary phosphonium salts based on quinopimaric acid // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 113-115.
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TY - JOUR
DO - 10.1016/j.mencom.2024.01.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.034
TI - Quaternary phosphonium salts based on quinopimaric acid
T2 - Mendeleev Communications
AU - Shinkareva, Anastasiya M
AU - Nemtarev, Andrey Vladimirovich
AU - Chachkov, Denis Vladimirovich
AU - Dobrynin, Alexey Borisovich
AU - Litvinov, Igor Anatol'evich
AU - Mironov, Vladimir Fedorovich
PY - 2023
DA - 2023/12/25
PB - Mendeleev Communications
SP - 113-115
IS - 1
VL - 34
ER -
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@article{2023_Shinkareva,
author = {Anastasiya M Shinkareva and Andrey Vladimirovich Nemtarev and Denis Vladimirovich Chachkov and Alexey Borisovich Dobrynin and Igor Anatol'evich Litvinov and Vladimir Fedorovich Mironov},
title = {Quaternary phosphonium salts based on quinopimaric acid},
journal = {Mendeleev Communications},
year = {2023},
volume = {34},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.034},
number = {1},
pages = {113--115},
doi = {10.1016/j.mencom.2024.01.034}
}
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Shinkareva, Anastasiya M., et al. “Quaternary phosphonium salts based on quinopimaric acid.” Mendeleev Communications, vol. 34, no. 1, Dec. 2023, pp. 113-115. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.034.
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Keywords

addition reaction.
phosphine quaternization
phosphonium salts
quinones
quinopimaric acid
α
β-unsaturated γ-diketones

Abstract

The reaction of quinopimaric acid with P-H-phosphonium salts yielded quaternary phosphonium salts containing enol moiety at the phosphorus atom. The reaction proceeded with high regioselectivity. The structures of the resulting compounds were confirmed by NMR and IR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction.

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