Home / Publications / Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions

Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions

Viktor Alekseevich Safonov 1
Viktor Alekseevich Safonov
, 
Maria Alekseevna Choba 1
Maria Alekseevna Choba
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2024.01.025
Published 2023-12-25
Communication , Volume 34, Issue 1, 85-87
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Safonov V. A., Choba M. A. Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 85-87.
GOST all authors (up to 50) Copy
Safonov V. A., Choba M. A. Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 85-87.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2024.01.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.025
TI - Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions
T2 - Mendeleev Communications
AU - Safonov, Viktor Alekseevich
AU - Choba, Maria Alekseevna
PY - 2023
DA - 2023/12/25
PB - Mendeleev Communications
SP - 85-87
IS - 1
VL - 34
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Safonov,
author = {Viktor Alekseevich Safonov and Maria Alekseevna Choba},
title = {Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions},
journal = {Mendeleev Communications},
year = {2023},
volume = {34},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.025},
number = {1},
pages = {85--87},
doi = {10.1016/j.mencom.2024.01.025}
}
MLA
Cite this
MLA Copy
Safonov, Viktor Alekseevich, and Maria Alekseevna Choba. “Electrical double layer at the interface of a Pb electrode with propylene carbonate solutions.” Mendeleev Communications, vol. 34, no. 1, Dec. 2023, pp. 85-87. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.025.
Views / Downloads
1 / 1

Keywords

electrical double layer (EDL)
impedance method
mechanically renewable Pb electrode
model description.
propylene carbonate
surface-inactive electrolyte

Abstract

The capacitance of the electrical double layer was measured in situ on a renewable Pb electrode in solutions of Bu4NClO4 in propylene carbonate (PC). The results and published data were analyzed using correlational relationships between the zero charge potentials (Eσ=0) of Hg, Pb, Sn, and Ga electrodes in solutions of surface-inactive electrolytes in PC, acetonitrile, and water on the one hand and the electron work functions of these metals (We) on the other hand. It was concluded that Pb electrodes interacted weakly with the molecules of these solvents.

References

.
The relation between the potential of zero charge and work function for sp-metals
Emets V.V., Damaskin B.B.
Russian Journal of Electrochemistry, 2009
.
Electrical Double Layer at a Liquid Pb–Ga Electrode in Propylene Carbonate Solutions
Emets V.V., Damaskin B.B., Bagotskaya I.A.
Russian Journal of Electrochemistry, 2001
.
Pb-sandwiched nanoparticles as anode material for lithium-ion batteries
Chen Z., Cao Y., Qian J., Ai X., Yang H.
Journal of Solid State Electrochemistry, 2011
.
Pb-Doped Lithium-Rich Cathode Material for High Energy Density Lithium-Ion Full Batteries
Zhang X., Xiong Y., Dong M., Hou Z.
Journal of the Electrochemical Society, 2019