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Stereoselective synthesis of functionalized hexene oligomers catalyzed by chiral ansa-zirconocene in the presence of Al- and B-containing activators

Pavel Victorovich Kovyazin 1
Pavel Victorovich Kovyazin
, 
Olesya V Mukhamadeeva 1
Olesya V Mukhamadeeva
, 
Lyudmila Vyacheslavovna Parfenova 1
Lyudmila Vyacheslavovna Parfenova
1 Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
10.1016/j.mencom.2024.01.018
Published 2023-12-25
Communication , Volume 34, Issue 1, 61-63
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Kovyazin P. V., Mukhamadeeva O. V., Parfenova L. V. Stereoselective synthesis of functionalized hexene oligomers catalyzed by chiral ansa-zirconocene in the presence of Al- and B-containing activators // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 61-63.
GOST all authors (up to 50) Copy
Kovyazin P. V., Mukhamadeeva O. V., Parfenova L. V. Stereoselective synthesis of functionalized hexene oligomers catalyzed by chiral ansa-zirconocene in the presence of Al- and B-containing activators // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 61-63.
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TY - JOUR
DO - 10.1016/j.mencom.2024.01.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.018
TI - Stereoselective synthesis of functionalized hexene oligomers catalyzed by chiral ansa-zirconocene in the presence of Al- and B-containing activators
T2 - Mendeleev Communications
AU - Kovyazin, Pavel Victorovich
AU - Mukhamadeeva, Olesya V
AU - Parfenova, Lyudmila Vyacheslavovna
PY - 2023
DA - 2023/12/25
PB - Mendeleev Communications
SP - 61-63
IS - 1
VL - 34
ER -
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@article{2023_Kovyazin,
author = {Pavel Victorovich Kovyazin and Olesya V Mukhamadeeva and Lyudmila Vyacheslavovna Parfenova},
title = {Stereoselective synthesis of functionalized hexene oligomers catalyzed by chiral ansa-zirconocene in the presence of Al- and B-containing activators},
journal = {Mendeleev Communications},
year = {2023},
volume = {34},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.018},
number = {1},
pages = {61--63},
doi = {10.1016/j.mencom.2024.01.018}
}
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Kovyazin, Pavel Victorovich, et al. “Stereoselective synthesis of functionalized hexene oligomers catalyzed by chiral ansa-zirconocene in the presence of Al- and B-containing activators.” Mendeleev Communications, vol. 34, no. 1, Dec. 2023, pp. 61-63. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.018.
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Keywords

(S)-(+)-α-methoxy-α-(trifluoro- methyl)phenylacetyl chloride.
alkenes
methylaluminoxane
oligomerization
stereoselective synthesis
zirconocenes

Abstract

Enantiomerically enriched (38-93% ee) diastereomerically pure (99% dr) functionally substituted dimers and oligomers with the starting Me-group were obtained by the reaction of 1-hexene with AlMe3 in the presence of enantiomerically pure dichloro[(R,R)-ethylenebis(4,5,6,7-tetrahydroinden-1-yl)]- zirconium(IV). Modified methylaluminoxane MMAO-12 as the activator was somewhat superior to boron-containing compound [Ph3C][B(C6F5)4].

References

.
Non-traditional Ziegler-Natta catalysis in α-olefin transformations: Reaction mechanisms and product design
Nifant’ev I., Ivchenko P., Tavtorkin A., Vinogradov A., Vinogradov A.
Pure and Applied Chemistry, 2017
.
Asymmetric hydrooligomerization of propylene
Pino P., Cioni P., Wei J.
Journal of the American Chemical Society, 1987
.
Intramolecular mobility of η5-ligands in chiral zirconocene complexes and the enantioselectivity of alkene functionalization by organoaluminum compounds
Parfenova L.V., Zakirova I.V., Kovyazin P.V., Karchevsky S.G., Istomina G.P., Khalilov L.M., Dzhemilev U.M.
Dalton Transactions, 2016
.
Catalytic enantioselective ethylalumination of terminal alkenes: Substrate effects and absolute configuration assignment
Parfenova L.V., Kovyazin P.V., Tyumkina T.V., Makrushina A.V., Khalilov L.M., Dzhemilev U.M.
Tetrahedron Asymmetry, 2015
.
One-step catalytic asymmetric synthesis of all-syn deoxypropionate motif from propylene: Total synthesis of (2R,4R,6R,8R)-2,4,6,8-tetramethyldecanoic acid
Ota Y., Murayama T., Nozaki K.
Proceedings of the National Academy of Sciences of the United States of America, 2016
.
The methyl-branched fortifications of Mycobacterium tuberculosis.
Minnikin D.E., Kremer L., Dover L.G., Besra G.S.
Chemistry & Biology, 2002
.
Iterative strategies for the synthesis of deoxypropionates.
ter Horst B., Feringa B.L., Minnaard A.J.
Chemical Communications, 2010
.
Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid.
Xu S., Oda A., Bobinski T., Li H., Matsueda Y., Negishi E.
Angewandte Chemie - International Edition, 2015
.
Kinetic Resolution of Chiral α-Olefins Using Optically Active ansa-Zirconocene Polymerization Catalysts
Baar C.R., Levy C.J., Min E.Y., Henling L.M., Day M.W., Bercaw J.E.
Journal of the American Chemical Society, 2004
.
Do New Century Catalysts Unravel the Mechanism of Stereocontrol of Old Ziegler−Natta Catalysts?
Corradini P., Guerra G., Cavallo L.
Accounts of Chemical Research, 2004
.
Chiral methyl-branched pheromones
Ando T., Yamakawa R.
Natural Product Reports, 2015
.
Collective Synthesis of 4-Hydroxy-2-pyridone Alkaloids and Their Antiproliferation Activities
Ding F., Leow M.L., Ma J., William R., Liao H., Liu X.
Chemistry - An Asian Journal, 2014
.
Enantioselective C–C bond formation in styrene dimerization with chiral ansa zirconocene-based catalyst
Galdi N., Monica C.D., Spinella A., Oliva L.
Journal of Molecular Catalysis A Chemical, 2006