A new efficient synthesis of Pyrphos ligand

Kononevich, Yuriy Nikolaevich; Volodin, Alexander Dmitrievich; Korlyukov, Alexander Aleksandrovich; Brel, Valery Kuzmich; Muzafarov, Aziz Mansurovich

doi:10.1016/j.mencom.2024.01.015

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A new efficient synthesis of Pyrphos ligand

Yuriy Nikolaevich Kononevich ¹

Yuriy Nikolaevich Kononevich

,

Alexander Dmitrievich Volodin ¹

Alexander Dmitrievich Volodin

,

Alexander Aleksandrovich Korlyukov ¹

Alexander Aleksandrovich Korlyukov

0000-0002-5600-9886

,

Valery Kuzmich Brel ¹

Valery Kuzmich Brel

0000-0003-4645-3251

,

Aziz Mansurovich Muzafarov ^{1, 2}

Aziz Mansurovich Muzafarov

0000-0002-3050-3253

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

² N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2024.01.015

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Published 2023-12-25

Communication , Volume 34, Issue 1, 51-53

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Kononevich Y. N. et al. A new efficient synthesis of Pyrphos ligand // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 51-53.

GOST all authors (up to 50) Copy

Kononevich Y. N., Volodin A. D., Korlyukov A. A., Brel V. K., Muzafarov A. M. A new efficient synthesis of Pyrphos ligand // Mendeleev Communications. 2023. Vol. 34. No. 1. pp. 51-53.

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TY - JOUR

DO - 10.1016/j.mencom.2024.01.015

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.015

TI - A new efficient synthesis of Pyrphos ligand

T2 - Mendeleev Communications

AU - Kononevich, Yuriy Nikolaevich

AU - Volodin, Alexander Dmitrievich

AU - Korlyukov, Alexander Aleksandrovich

AU - Brel, Valery Kuzmich

AU - Muzafarov, Aziz Mansurovich

PY - 2023

DA - 2023/12/25

PB - Mendeleev Communications

SP - 51-53

IS - 1

VL - 34

ER -

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@article{2023_Kononevich,

author = {Yuriy Nikolaevich Kononevich and Alexander Dmitrievich Volodin and Alexander Aleksandrovich Korlyukov and Valery Kuzmich Brel and Aziz Mansurovich Muzafarov},

title = {A new efficient synthesis of Pyrphos ligand},

journal = {Mendeleev Communications},

year = {2023},

volume = {34},

publisher = {Mendeleev Communications},

month = {Dec},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.015},

number = {1},

pages = {51--53},

doi = {10.1016/j.mencom.2024.01.015}

}

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Kononevich, Yuriy Nikolaevich, et al. “A new efficient synthesis of Pyrphos ligand.” Mendeleev Communications, vol. 34, no. 1, Dec. 2023, pp. 51-53. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2024.01.015.

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Keywords

aza-Michael addition

intramolecular cyclization

phosphines

Pyrphos

reduction

X-ray analysis.

Abstract

A new efficient synthesis of racemic (R*,R*)-Pyrphos ligand based on aza-Michael addition reaction of 2,3-bis(diphenylphosphoryl)buta-1,3-diene with ammonia followed by the reduction of resulting 3,4-bis(diphenylphosphoryl)pyrrolidine is proposed. The starting reactants are available but-2-yne-1,4-diol and chloro(diphenyl)phosphine.

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