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Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping

Timur Zinnurovich Sharifullin 1
Timur Zinnurovich Sharifullin
, 
Alexander Vital'evich Vasiliev 1
Alexander Vital'evich Vasiliev
, 
Artem Anatol'evich Eliseev 1
Artem Anatol'evich Eliseev
,  , 
Sebastian Bette 2
Sebastian Bette
, 
Robert E Dinnebier 2
Robert E Dinnebier
, 
Reinhard K Kremer 2
Reinhard K Kremer
, 
Pavel Evgen'evich Kazin 1
Pavel Evgen'evich Kazin
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
2 Max Planck Institute for Solid State Research, Stuttgart, Germany
10.1016/j.mencom.2023.10.043
Published 2023-10-18
Communication , Volume 33, Issue 6, 866-868
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Sharifullin T. Z. et al. Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 866-868.
GOST all authors (up to 50) Copy
Sharifullin T. Z., Vasiliev A. V., Eliseev A. A., Eliseev A. A., Bette S., Dinnebier R. E., Kremer R. K., Kazin P. E. Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 866-868.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.043
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.043
TI - Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping
T2 - Mendeleev Communications
AU - Sharifullin, Timur Zinnurovich
AU - Vasiliev, Alexander Vital'evich
AU - Eliseev, Artem Anatol'evich
AU - Eliseev, Andrey Anatol'evich
AU - Bette, Sebastian
AU - Dinnebier, Robert E
AU - Kremer, Reinhard K
AU - Kazin, Pavel Evgen'evich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 866-868
IS - 6
VL - 33
ER -
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@article{2023_Sharifullin,
author = {Timur Zinnurovich Sharifullin and Alexander Vital'evich Vasiliev and Artem Anatol'evich Eliseev and Andrey Anatol'evich Eliseev and Sebastian Bette and Robert E Dinnebier and Reinhard K Kremer and Pavel Evgen'evich Kazin},
title = {Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.043},
number = {6},
pages = {866--868},
doi = {10.1016/j.mencom.2023.10.043}
}
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Sharifullin, Timur Zinnurovich, et al. “Formation of a single-ion magnet in the lanthanum calcium silicate apatite structure by the cobalt oxide doping.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 866-868. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.043.
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Keywords

apatite
crystal structure
magnetic properties.
silicate
single molecule magnet
single-ion magnet

Abstract

A small amount of cobalt was incorporated into the lanthanum calcium silicate apatite structure by annealing at 1500 °C in argon. The compound exhibits easy-axis magnetic anisotropy with a zero-field splitting parameter 2D of −60 cm−1 and field- induced slow relaxation of magnetization with a remagnetization energy barrier of 58-63 cm−1. Thereby, for the first time, a cobalt-based single-ion magnet was created in silicate.

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