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NiII and CuII coordination polymers as anode materials and their compatibility with different electrolytes in Li-ion batteries

Guzaliya Rafikovna Baymuratova 1
Guzaliya Rafikovna Baymuratova
, 
Ekaterina Andreevna Komissarova 1
Ekaterina Andreevna Komissarova
, 
Galiya Zaynetdinovna Tulibaeva 1
Galiya Zaynetdinovna Tulibaeva
,  , 
Olga Alexandrovna Kraevaya 1
Olga Alexandrovna Kraevaya
, 
Pavel Anatol'evich Troshin 1, 2, 3
Pavel Anatol'evich Troshin
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2 Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou, China
3 Harbin Institute of Technology, Harbin, China
10.1016/j.mencom.2023.10.041
Published 2023-10-18
Communication , Volume 33, Issue 6, 861-863
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Baymuratova G. R. et al. NiII and CuII coordination polymers as anode materials and their compatibility with different electrolytes in Li-ion batteries // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 861-863.
GOST all authors (up to 50) Copy
Baymuratova G. R., Komissarova E. A., Tulibaeva G. Z., Yarmolenko O. V., Kraevaya O. A., Troshin P. A. NiII and CuII coordination polymers as anode materials and their compatibility with different electrolytes in Li-ion batteries // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 861-863.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.041
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.041
TI - NiII and CuII coordination polymers as anode materials and their compatibility with different electrolytes in Li-ion batteries
T2 - Mendeleev Communications
AU - Baymuratova, Guzaliya Rafikovna
AU - Komissarova, Ekaterina Andreevna
AU - Tulibaeva, Galiya Zaynetdinovna
AU - Yarmolenko, Ol'ga Viktorovna
AU - Kraevaya, Olga Alexandrovna
AU - Troshin, Pavel Anatol'evich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 861-863
IS - 6
VL - 33
ER -
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@article{2023_Baymuratova,
author = {Guzaliya Rafikovna Baymuratova and Ekaterina Andreevna Komissarova and Galiya Zaynetdinovna Tulibaeva and Ol'ga Viktorovna Yarmolenko and Olga Alexandrovna Kraevaya and Pavel Anatol'evich Troshin},
title = {NiII and CuII coordination polymers as anode materials and their compatibility with different electrolytes in Li-ion batteries},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.041},
number = {6},
pages = {861--863},
doi = {10.1016/j.mencom.2023.10.041}
}
MLA
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MLA Copy
Baymuratova, Guzaliya Rafikovna, et al. “NiII and CuII coordination polymers as anode materials and their compatibility with different electrolytes in Li-ion batteries.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 861-863. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.041.

Keywords

dioxolane.
discharge capacity
in situ polymerized electrolyte
LiPF6
lithium battery
MOF

Abstract

The effect of various types of electrolytes on the operation of coordination polymers based on NiII or CuII in lithium-ion batteries has been examined. Cyclic voltammetry, galvanostatic cycling and quantum chemical modeling have been used to study the processes of lithiation and delithiation. It was shown that the use of a new electrolyte based on a mixture of 1 M LiN(CF3SO2)2 in 1,3-dioxolane-1,2-dimethoxyethane and 1 M LiPF6 in ethylene carbonate-dimethyl carbonate improved battery performance, while cycling in the range of 0.2-2.5 V increased the discharge capacity up to 177-188 mA h g−1 and stabilized the charge-discharge processes.

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