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HMFI/SiC - A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion

Alexey Georgievich Dedov 1, 2
Alexey Georgievich Dedov
, 
Alexander Alexandrovich Karavaev 1, 2
Alexander Alexandrovich Karavaev
, 
Alexey Sergeevich Loktev 1, 2
Alexey Sergeevich Loktev
, 
Petr Vital'evich Zemlianskii 2
Petr Vital'evich Zemlianskii
, 
Malika Nasrudinovna Vagapova 1
Malika Nasrudinovna Vagapova
,  , 
Kirill Alekseevich Cherednichenko 2
Kirill Alekseevich Cherednichenko
, 
Sergey Vladimirovich Egazaryants 3
Sergey Vladimirovich Egazaryants
, 
Alexey Vladimirovich Khoroshilov 4
Alexey Vladimirovich Khoroshilov
, 
1 A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
2 National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation
3 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
4 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
10.1016/j.mencom.2023.10.031
Published 2023-10-18
Communication , Volume 33, Issue 6, 832-835
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Dedov A. G. et al. HMFI/SiC - A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 832-835.
GOST all authors (up to 50) Copy
Dedov A. G., Karavaev A. A., Loktev A. S., Zemlianskii P. V., Vagapova M. N., Maslakov K. I., Cherednichenko K. A., Egazaryants S. V., Khoroshilov A. V., Ivanov P. I. HMFI/SiC - A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 832-835.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.031
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.031
TI - HMFI/SiC - A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion
T2 - Mendeleev Communications
AU - Dedov, Alexey Georgievich
AU - Karavaev, Alexander Alexandrovich
AU - Loktev, Alexey Sergeevich
AU - Zemlianskii, Petr Vital'evich
AU - Vagapova, Malika Nasrudinovna
AU - Maslakov, Konstantin Igorevich
AU - Cherednichenko, Kirill Alekseevich
AU - Egazaryants, Sergey Vladimirovich
AU - Khoroshilov, Alexey Vladimirovich
AU - Ivanov, Pavel Igorevich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 832-835
IS - 6
VL - 33
ER -
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@article{2023_Dedov,
author = {Alexey Georgievich Dedov and Alexander Alexandrovich Karavaev and Alexey Sergeevich Loktev and Petr Vital'evich Zemlianskii and Malika Nasrudinovna Vagapova and Konstantin Igorevich Maslakov and Kirill Alekseevich Cherednichenko and Sergey Vladimirovich Egazaryants and Alexey Vladimirovich Khoroshilov and Pavel Igorevich Ivanov},
title = {HMFI/SiC - A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.031},
number = {6},
pages = {832--835},
doi = {10.1016/j.mencom.2023.10.031}
}
MLA
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Dedov, Alexey Georgievich, et al. “HMFI/SiC - A novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 832-835. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.031.

Keywords

‘green’ hydrocarbons.
arenes
C2–C4 olefins
catalysis
HMFI/SiC composite
isobutanol
propylene

Abstract

Conversion of isobutyl alcohol over the HMFI/SiC composite has been for the first time studied. Isobutanol (bioisobutanol) considered as a promising product of biomass processing was catalytically converted into aromatic hydrocarbons of the benzene-toluene-xylene fraction (BTX) and olefins C2-C4 (mainly propylene and butenes). Compared with the pure zeolite, the incorporation of HMFI into the SiC matrix enhanced the yields of C2-C4 olefins and BTX in the isobutanol conversion due to increased densities of Bronsted and Lewis acid centers

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